Zn-containing double complex salts formed by Keggin type polyoxotungstates: Synthesis and crystal structure

L. I. Udalova; S. A. Adonin; P. A. Abramov; I. V. Korolkov; M. N. Sokolov

doi:10.1134/S1070328417050086

Zn-containing double complex salts formed by Keggin type polyoxotungstates: Synthesis and crystal structure

L. I. Udalova, S. A. Adonin, P. A. Abramov, I. V. Korolkov, M. N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

Novel double complex salts, [Zn(DMF)₆]₂[SiW₁₂O₄₀] · 2H₂O (I) and [Zn(H₂O)₂(DMF)₄][Zn(DMF)₆]₂[PW₁₂O₄₀]₂ · 6DMF (II) (DMF = N,N-dimethylformamide), were prepared by the reaction of Zn²⁺ and heteropoly acids H_x[EW₁₂O₄₀] · xH₂O (E = P, X = 3, E = Si, X = 4) in DMF. Compounds I and II were studied by X-ray diffraction (СIF files CCDC nos. 1497570 (I) and 1497571 (II)) and IR spectroscopy.

Язык оригинала	английский
Страницы (с-по)	368-372
Число страниц	5
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	43
Номер выпуска	6
DOI	https://doi.org/10.1134/S1070328417050086
Состояние	Опубликовано - 1 июн 2017

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10.1134/S1070328417050086

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title = "Zn-containing double complex salts formed by Keggin type polyoxotungstates: Synthesis and crystal structure",

abstract = "Novel double complex salts, [Zn(DMF)6]2[SiW12O40] · 2H2O (I) and [Zn(H2O)2(DMF)4][Zn(DMF)6]2[PW12O40]2 · 6DMF (II) (DMF = N,N-dimethylformamide), were prepared by the reaction of Zn2+ and heteropoly acids Hx[EW12O40] · xH2O (E = P, X = 3, E = Si, X = 4) in DMF. Compounds I and II were studied by X-ray diffraction (СIF files CCDC nos. 1497570 (I) and 1497571 (II)) and IR spectroscopy.",

keywords = "crystal structure, double complex salts, polyoxometalates, zinc, NETWORK, PERFORMANCE, MAGNETIC-PROPERTY, POLYOXOMETALATE HYBRIDS, MILD, OXIDATIVE DESULFURIZATION, POLYMER, HYDROGEN-PEROXIDE, METAL, CATALYSTS",

author = "Udalova, {L. I.} and Adonin, {S. A.} and Abramov, {P. A.} and Korolkov, {I. V.} and Sokolov, {M. N.}",

year = "2017",

month = jun,

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doi = "10.1134/S1070328417050086",

language = "English",

volume = "43",

pages = "368--372",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

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Zn-containing double complex salts formed by Keggin type polyoxotungstates : Synthesis and crystal structure. / Udalova, L. I.; Adonin, S. A.; Abramov, P. A.; Korolkov, I. V.; Sokolov, M. N.

В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 43, № 6, 01.06.2017, стр. 368-372.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Zn-containing double complex salts formed by Keggin type polyoxotungstates

T2 - Synthesis and crystal structure

AU - Udalova, L. I.

AU - Adonin, S. A.

AU - Abramov, P. A.

AU - Korolkov, I. V.

AU - Sokolov, M. N.

PY - 2017/6/1

Y1 - 2017/6/1

N2 - Novel double complex salts, [Zn(DMF)6]2[SiW12O40] · 2H2O (I) and [Zn(H2O)2(DMF)4][Zn(DMF)6]2[PW12O40]2 · 6DMF (II) (DMF = N,N-dimethylformamide), were prepared by the reaction of Zn2+ and heteropoly acids Hx[EW12O40] · xH2O (E = P, X = 3, E = Si, X = 4) in DMF. Compounds I and II were studied by X-ray diffraction (СIF files CCDC nos. 1497570 (I) and 1497571 (II)) and IR spectroscopy.

AB - Novel double complex salts, [Zn(DMF)6]2[SiW12O40] · 2H2O (I) and [Zn(H2O)2(DMF)4][Zn(DMF)6]2[PW12O40]2 · 6DMF (II) (DMF = N,N-dimethylformamide), were prepared by the reaction of Zn2+ and heteropoly acids Hx[EW12O40] · xH2O (E = P, X = 3, E = Si, X = 4) in DMF. Compounds I and II were studied by X-ray diffraction (СIF files CCDC nos. 1497570 (I) and 1497571 (II)) and IR spectroscopy.

KW - crystal structure

KW - double complex salts

KW - polyoxometalates

KW - zinc

KW - NETWORK

KW - PERFORMANCE

KW - MAGNETIC-PROPERTY

KW - POLYOXOMETALATE HYBRIDS

KW - MILD

KW - OXIDATIVE DESULFURIZATION

KW - POLYMER

KW - HYDROGEN-PEROXIDE

KW - METAL

KW - CATALYSTS

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U2 - 10.1134/S1070328417050086

DO - 10.1134/S1070328417050086

M3 - Article

AN - SCOPUS:85020658520

VL - 43

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EP - 372

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

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ER -