Аннотация
The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core.
Язык оригинала | английский |
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Страницы (с-по) | 1166-1172 |
Число страниц | 7 |
Журнал | Journal of Structural Chemistry |
Том | 58 |
Номер выпуска | 6 |
DOI | |
Состояние | Опубликовано - 1 ноя 2017 |