X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes

A. D. Fedorenko; L. N. Mazalov; E. Yu Fursova; V. I. Ovcharenko; A. V. Kalinkin; S. A. Lavrukhina

doi:10.1134/S0022476617060142

X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes

A. D. Fedorenko, L. N. Mazalov, E. Yu Fursova, V. I. Ovcharenko, A. V. Kalinkin, S. A. Lavrukhina

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn₆(O)₂Piv₁₀] core.

Язык оригинала	английский
Страницы (с-по)	1166-1172
Число страниц	7
Журнал	Journal of Structural Chemistry
Том	58
Номер выпуска	6
DOI	https://doi.org/10.1134/S0022476617060142
Состояние	Опубликовано - 1 ноя 2017

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10.1134/S0022476617060142

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title = "X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes",

abstract = "The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core.",

keywords = "manganese pivalate with isonicotinamide, XES, XPS",

author = "Fedorenko, {A. D.} and Mazalov, {L. N.} and Fursova, {E. Yu} and Ovcharenko, {V. I.} and Kalinkin, {A. V.} and Lavrukhina, {S. A.}",

year = "2017",

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doi = "10.1134/S0022476617060142",

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X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes. / Fedorenko, A. D.; Mazalov, L. N.; Fursova, E. Yu; Ovcharenko, V. I.; Kalinkin, A. V.; Lavrukhina, S. A.

В: Journal of Structural Chemistry, Том 58, № 6, 01.11.2017, стр. 1166-1172.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes

AU - Fedorenko, A. D.

AU - Mazalov, L. N.

AU - Fursova, E. Yu

AU - Ovcharenko, V. I.

AU - Kalinkin, A. V.

AU - Lavrukhina, S. A.

PY - 2017/11/1

Y1 - 2017/11/1

N2 - The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core.

AB - The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core.

KW - manganese pivalate with isonicotinamide

KW - XES

KW - XPS

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U2 - 10.1134/S0022476617060142

DO - 10.1134/S0022476617060142

M3 - Article

AN - SCOPUS:85036582913

VL - 58

SP - 1166

EP - 1172

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -