WS2/MoS2 Heterostructures through Thermal Treatment of MoS2 Layers Electrostatically Functionalized with W3S4 Molecular Clusters

Marc Morant-Giner, Isaac Brotons-Alcázar, Nikita Y. Shmelev, Artem L. Gushchin, Luke T. Norman, Andrei N. Khlobystov, Antonio Alberola, Sergio Tatay, Josep Canet-Ferrer, Alicia Forment-Aliaga, Eugenio Coronado

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

The preparation of 2D stacked layers combining flakes of different nature gives rise to countless numbers of heterostructures where new band alignments, defined at the interfaces, control the electronic properties of the system. Among the large family of 2D/2D heterostructures, the one formed by the combination of the most common semiconducting transition metal dichalcogenides, WS2/MoS2, has awakened great interest owing to its photovoltaic and photoelectrochemical properties. Solution as well as dry physical methods have been developed to optimize the synthesis of these heterostructures. Here, a suspension of negatively charged MoS2 flakes is mixed with a methanolic solution of a cationic W3S4-core cluster, giving rise to a homogeneous distribution of the clusters over the layers. In a second step, a calcination of this molecular/2D heterostructure under N2 leads to the formation of clean WS2/MoS2 heterostructures, where the photoluminescence of both counterparts is quenched, proving an efficient interlayer coupling. Thus, this chemical method combines the advantages of a solution approach (simple, scalable, and low-cost) with the good quality interfaces reached by using more complicated traditional physical methods.

Язык оригиналаанглийский
Страницы (с-по)6670-6678
Число страниц9
ЖурналChemistry - A European Journal
Том26
Номер выпуска29
DOI
СостояниеОпубликовано - 20 мая 2020

Fingerprint Подробные сведения о темах исследования «WS<sub>2</sub>/MoS<sub>2</sub> Heterostructures through Thermal Treatment of MoS<sub>2</sub> Layers Electrostatically Functionalized with W<sub>3</sub>S<sub>4</sub> Molecular Clusters». Вместе они формируют уникальный семантический отпечаток (fingerprint).

  • Цитировать

    Morant-Giner, M., Brotons-Alcázar, I., Shmelev, N. Y., Gushchin, A. L., Norman, L. T., Khlobystov, A. N., Alberola, A., Tatay, S., Canet-Ferrer, J., Forment-Aliaga, A., & Coronado, E. (2020). WS2/MoS2 Heterostructures through Thermal Treatment of MoS2 Layers Electrostatically Functionalized with W3S4 Molecular Clusters. Chemistry - A European Journal, 26(29), 6670-6678. https://doi.org/10.1002/chem.202000248