Water-soluble Re                         
                        6
                                                 -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications

Anton A. Ivanov; Dmitry I. Konovalov; Tatiana N. Pozmogova; Anastasiya O. Solovieva; Anatoly R. Melnikov; Konstantin A. Brylev; Natalia V. Kuratieva; Vadim V. Yanshole; Kaplan Kirakci; Kamil Lang; Svetlana N. Cheltygmasheva; Noboru Kitamura; Lidiya V. Shestopalova; Yuri V. Mironov; Michael A. Shestopalov

doi:10.1039/c8qi01216d

Water-soluble Re ₆ -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications

Anton A. Ivanov, Dmitry I. Konovalov, Tatiana N. Pozmogova, Anastasiya O. Solovieva, Anatoly R. Melnikov, Konstantin A. Brylev, Natalia V. Kuratieva, Vadim V. Yanshole, Kaplan Kirakci, Kamil Lang, Svetlana N. Cheltygmasheva, Noboru Kitamura, Lidiya V. Shestopalova, Yuri V. Mironov, Michael A. Shestopalov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

21 Цитирования (Scopus)

Аннотация

The development of water-soluble hexanuclear cluster complexes of low toxicity is a promising task due to their potential biomedical applications such as bioimaging and photodynamic therapy. Herein, we present the syntheses of two new water-soluble hexarhenium cluster complexes with terminal amphiphilic phosphine ligands, and delineate their photoluminescence and X-ray excited optical luminescence (XEOL) properties. These cluster complexes, namely [{Re ₆ Q ₈ }(PPh ₂ CH ₂ CH ₂ COO) ₆ ] ^4- (Q = S (1); Se, (2)), have the least cytotoxicity among all the tested hexanuclear metal-clusters, are capable of penetrating into cells and exhibit moderate photodynamic toxicity toward Hep-2 cells.

Язык оригинала	английский
Страницы (с-по)	882-892
Число страниц	11
Журнал	Inorganic Chemistry Frontiers
Том	6
Номер выпуска	4
DOI	https://doi.org/10.1039/c8qi01216d
Состояние	Опубликовано - 1 апр. 2019

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10.1039/c8qi01216d

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Ivanov, A. A., Konovalov, D. I., Pozmogova, T. N., Solovieva, A. O., Melnikov, A. R., Brylev, K. A., Kuratieva, N. V., Yanshole, V. V., Kirakci, K., Lang, K., Cheltygmasheva, S. N., Kitamura, N., Shestopalova, L. V., Mironov, Y. V., & Shestopalov, M. A. (2019). Water-soluble Re ₆ -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications. Inorganic Chemistry Frontiers, 6(4), 882-892. https://doi.org/10.1039/c8qi01216d

@article{f1eec265920542d9aee410414539dd18,

title = "Water-soluble Re 6 -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications",

abstract = " The development of water-soluble hexanuclear cluster complexes of low toxicity is a promising task due to their potential biomedical applications such as bioimaging and photodynamic therapy. Herein, we present the syntheses of two new water-soluble hexarhenium cluster complexes with terminal amphiphilic phosphine ligands, and delineate their photoluminescence and X-ray excited optical luminescence (XEOL) properties. These cluster complexes, namely [{Re 6 Q 8 }(PPh 2 CH 2 CH 2 COO) 6 ] 4- (Q = S (1); Se, (2)), have the least cytotoxicity among all the tested hexanuclear metal-clusters, are capable of penetrating into cells and exhibit moderate photodynamic toxicity toward Hep-2 cells. ",

author = "Ivanov, {Anton A.} and Konovalov, {Dmitry I.} and Pozmogova, {Tatiana N.} and Solovieva, {Anastasiya O.} and Melnikov, {Anatoly R.} and Brylev, {Konstantin A.} and Kuratieva, {Natalia V.} and Yanshole, {Vadim V.} and Kaplan Kirakci and Kamil Lang and Cheltygmasheva, {Svetlana N.} and Noboru Kitamura and Shestopalova, {Lidiya V.} and Mironov, {Yuri V.} and Shestopalov, {Michael A.}",

note = "Publisher Copyright: {\textcopyright} 2019 the Partner Organisations.",

year = "2019",

month = apr,

day = "1",

doi = "10.1039/c8qi01216d",

language = "English",

volume = "6",

pages = "882--892",

journal = "Inorganic Chemistry Frontiers",

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Ivanov, AA, Konovalov, DI, Pozmogova, TN, Solovieva, AO, Melnikov, AR , Brylev, KA , Kuratieva, NV , Yanshole, VV, Kirakci, K, Lang, K, Cheltygmasheva, SN, Kitamura, N, Shestopalova, LV, Mironov, YV & Shestopalov, MA 2019, 'Water-soluble Re ₆ -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications', Inorganic Chemistry Frontiers, том. 6, № 4, стр. 882-892. https://doi.org/10.1039/c8qi01216d

Water-soluble Re ₆ -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications. / Ivanov, Anton A.; Konovalov, Dmitry I.; Pozmogova, Tatiana N. и др.

В: Inorganic Chemistry Frontiers, Том 6, № 4, 01.04.2019, стр. 882-892.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Water-soluble Re 6 -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications

AU - Ivanov, Anton A.

AU - Konovalov, Dmitry I.

AU - Pozmogova, Tatiana N.

AU - Solovieva, Anastasiya O.

AU - Melnikov, Anatoly R.

AU - Brylev, Konstantin A.

AU - Kuratieva, Natalia V.

AU - Yanshole, Vadim V.

AU - Kirakci, Kaplan

AU - Lang, Kamil

AU - Cheltygmasheva, Svetlana N.

AU - Kitamura, Noboru

AU - Shestopalova, Lidiya V.

AU - Mironov, Yuri V.

AU - Shestopalov, Michael A.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - The development of water-soluble hexanuclear cluster complexes of low toxicity is a promising task due to their potential biomedical applications such as bioimaging and photodynamic therapy. Herein, we present the syntheses of two new water-soluble hexarhenium cluster complexes with terminal amphiphilic phosphine ligands, and delineate their photoluminescence and X-ray excited optical luminescence (XEOL) properties. These cluster complexes, namely [{Re 6 Q 8 }(PPh 2 CH 2 CH 2 COO) 6 ] 4- (Q = S (1); Se, (2)), have the least cytotoxicity among all the tested hexanuclear metal-clusters, are capable of penetrating into cells and exhibit moderate photodynamic toxicity toward Hep-2 cells.

AB - The development of water-soluble hexanuclear cluster complexes of low toxicity is a promising task due to their potential biomedical applications such as bioimaging and photodynamic therapy. Herein, we present the syntheses of two new water-soluble hexarhenium cluster complexes with terminal amphiphilic phosphine ligands, and delineate their photoluminescence and X-ray excited optical luminescence (XEOL) properties. These cluster complexes, namely [{Re 6 Q 8 }(PPh 2 CH 2 CH 2 COO) 6 ] 4- (Q = S (1); Se, (2)), have the least cytotoxicity among all the tested hexanuclear metal-clusters, are capable of penetrating into cells and exhibit moderate photodynamic toxicity toward Hep-2 cells.

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U2 - 10.1039/c8qi01216d

DO - 10.1039/c8qi01216d

M3 - Article

AN - SCOPUS:85063429787

VL - 6

SP - 882

EP - 892

JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

SN - 2052-1545

IS - 4

ER -

Ivanov AA, Konovalov DI, Pozmogova TN, Solovieva AO, Melnikov AR , Brylev KA и др. Water-soluble Re ₆ -clusters with aromatic phosphine ligands-from synthesis to potential biomedical applications. Inorganic Chemistry Frontiers. 2019 апр. 1;6(4):882-892. https://doi.org/10.1039/c8qi01216d