Versatile approach to activation of alkoxyamine homolysis by 1,3-dipolar cycloaddition for efficient and safe nitroxide mediated polymerization

Mariya Edeleva, Denis Morozov, Dmitriy Parkhomenko, Yulia Polienko, Anna Iurchenkova, Igor Kirilyuk, Elena Bagryanskaya

Результат исследования: Научные публикации в периодических изданияхстатья

2 Цитирования (Scopus)

Аннотация

An alkoxyamine was prepared from a cyclic aldonitrone nitroxide. The resulting alkoxyamine containing an aldonitrone functional substituent is relatively stable but can react readily with vinyl monomers to form a cycloadduct that has a much higher C-ON homolysis rate. This type of in situ activation converts the aldonitrone alkoxyamine into an efficient controlling agent for nitroxide-mediated polymerization. Here we present a study on this reaction of C-ON bond homolysis and application of such an alkoxyamine as an in situ-activated initiator.

Язык оригиналаанглийский
Страницы (с-по)190-193
Число страниц4
ЖурналChemical Communications
Том55
Номер выпуска2
DOI
СостояниеОпубликовано - 1 янв 2019

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