Аннотация
An alkoxyamine was prepared from a cyclic aldonitrone nitroxide. The resulting alkoxyamine containing an aldonitrone functional substituent is relatively stable but can react readily with vinyl monomers to form a cycloadduct that has a much higher C-ON homolysis rate. This type of in situ activation converts the aldonitrone alkoxyamine into an efficient controlling agent for nitroxide-mediated polymerization. Here we present a study on this reaction of C-ON bond homolysis and application of such an alkoxyamine as an in situ-activated initiator.
Язык оригинала | английский |
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Страницы (с-по) | 190-193 |
Число страниц | 4 |
Журнал | Chemical Communications |
Том | 55 |
Номер выпуска | 2 |
DOI | |
Состояние | Опубликовано - 1 янв 2019 |