Unique shortening of carbon chain during reduction of aliphatic nitro compounds to amines in the presence of supercritical isopropanol on alumina

V. P. Sivcev, K. P. Volcho, N. F. Salakhutdinov, V. I. Anikeev

Результат исследования: Научные публикации в периодических изданияхстатья

2 Цитирования (Scopus)

Аннотация

Transformations of lower aliphatic nitrocompounds in supercritical isopropanol in a flow reactor in the presence of alumina were studied. In experiments with 1-nitropropane, the dominant process was the never-before-observed formation of an amine with a shorter by one carbon atom chain as compared to the initial nitroalkane. The reaction mechanism was suggested which adequately explained the formation of all detected products. The reactions of nitroethane and nitromethane partly proceeded by a new transformation route yielding isopropylamine.

Язык оригиналаанглийский
ЖурналJournal of Supercritical Fluids
Том103
DOI
СостояниеОпубликовано - 28 июл 2015

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