Two oxygen-coordinated metastable Ru-ON states for ruthenium mononitrosyl complex

Результат исследования: Научные публикации в периодических изданияхстатьярецензирование

16 Цитирования (Scopus)


The properties of Ru-ON states were studied in cis-[RuNO(NH3)2(NO2)2OH] under illumination. The structure contains two nonequivalent complexes, and the metastable state was generated for both molecules with 19(1) and 31(1)% populations. The MS1 thermal decay occurs as a one-step process at about 240 K according to differential scanning calorimetry (DSC). For the first-order reaction, the frequency factor and activation energy for the decay process were determined as 2.0(2) × 1013 s-1 and 68.3(4) kJ mol-1, respectively. Also, the simultaneous metastable state decay observed via DSC was in agreement with IR spectroscopy.

Язык оригиналаанглийский
Страницы (с-по)9158-9161
Число страниц4
ЖурналInorganic Chemistry
Номер выпуска18
СостояниеОпубликовано - 19 сент. 2016


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