Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster

Anton A. Ivanov; Clément Falaise; David Landy; Mohamed Haouas; Yuri V. Mironov; Michael A. Shestopalov; Emmanuel Cadot

doi:10.1039/c9cc05136h

Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster

Anton A. Ivanov, Clément Falaise, David Landy, Mohamed Haouas, Yuri V. Mironov, Michael A. Shestopalov, Emmanuel Cadot

Лаборатория полиядерных координационных соединений ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья

6 Цитирования (Scopus)

Аннотация

We report how only one electron transfer from the hydrophilic reduced cluster [{Re₆Se₈}(CN)₆]^4- induces both a dramatic increase of the host-guest affinity with γ-cyclodextrin and a drastic alteration of the supramolecular dynamics. This striking behaviour, underlined by its thermochemical fingerprint, indicates that the self-assembly process is driven by a chaotropic effect.

Язык оригинала	английский
Страницы (с-по)	9951-9954
Число страниц	4
Журнал	Chemical Communications
Том	55
Номер выпуска	67
DOI	https://doi.org/10.1039/c9cc05136h
Состояние	Опубликовано - 28 авг 2019

Доступ к документу

10.1039/c9cc05136h

Link to publication in Scopus

Fingerprint Подробные сведения о темах исследования «Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать

Ivanov, A. A., Falaise, C., Landy, D., Haouas, M., Mironov, Y. V., Shestopalov, M. A., & Cadot, E. (2019). Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster. Chemical Communications, 55(67), 9951-9954. https://doi.org/10.1039/c9cc05136h

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abstract = "We report how only one electron transfer from the hydrophilic reduced cluster [{Re6Se8}(CN)6]4- induces both a dramatic increase of the host-guest affinity with γ-cyclodextrin and a drastic alteration of the supramolecular dynamics. This striking behaviour, underlined by its thermochemical fingerprint, indicates that the self-assembly process is driven by a chaotropic effect.",

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Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster. / Ivanov, Anton A.; Falaise, Clément; Landy, David; Haouas, Mohamed; Mironov, Yuri V.; Shestopalov, Michael A.; Cadot, Emmanuel.

В: Chemical Communications, Том 55, № 67, 28.08.2019, стр. 9951-9954.

Результат исследования: Научные публикации в периодических изданиях › статья

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