Transformations of the Bis(thiourea)gold(I) Complex in Alkaline Medium and Interaction of Thiourea with HAuCl4

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

The interaction of AuCl4 - with thiourea (tu) at various СtuAu ratios and transformations of the bis(thiourea)gold(I) complex in an alkaline aqueous solution have been studied. Both processes lead to a set of products. It has been demonstrated that formamidine disulfide is not the major product of thiourea oxidation. The precipitate forming upon the treatment of AuCl4 - with an alkali contains Au2S and an organic part, which is likely a polymeric compound [Au(tu-H)]n.

Язык оригиналаанглийский
Страницы (с-по)1667-1672
Число страниц6
ЖурналRussian Journal of Inorganic Chemistry
Том63
Номер выпуска12
DOI
СостояниеОпубликовано - 1 дек 2018

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