TY - JOUR
T1 - Transformation of a proton insulator to a conductor
T2 - Via reversible amorphous to crystalline structure transformation of MOFs
AU - Song, Yoodae
AU - Khudozhitkov, Alexander E.
AU - Lee, Jihyun
AU - Kang, Hyosik
AU - Kolokolov, Daniil I.
AU - Stepanov, Alexander G.
AU - Yoon, Minyoung
PY - 2020/4/25
Y1 - 2020/4/25
N2 - In this study, a successful proton conduction modulation of MOFs, from an ionic insulator to an ionic conductor, is demonstrated through their structural transformation. It is shown that the reversible structural change from amorphous to crystalline phases allows for the reversible proton conduction modulation of MOFs. Moreover, the proton conduction mechanism of the ionic conductor phase is elucidated by 2H NMR analysis.
AB - In this study, a successful proton conduction modulation of MOFs, from an ionic insulator to an ionic conductor, is demonstrated through their structural transformation. It is shown that the reversible structural change from amorphous to crystalline phases allows for the reversible proton conduction modulation of MOFs. Moreover, the proton conduction mechanism of the ionic conductor phase is elucidated by 2H NMR analysis.
KW - COORDINATION
KW - MAGNESIUM
UR - http://www.scopus.com/inward/record.url?scp=85083912966&partnerID=8YFLogxK
U2 - 10.1039/d0cc00755b
DO - 10.1039/d0cc00755b
M3 - Article
C2 - 32196036
AN - SCOPUS:85083912966
VL - 56
SP - 4468
EP - 4471
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 32
ER -