@inproceedings{bb3c9c0d1a3e4aaa9b04504191eb0bcc,
title = "Three-dimensional ion imaging study of PCl3photodissociation at 235 nm",
abstract = "The dynamics of photodissociation of PCl3 at 235 nm has been studied by monitoring of ground state Cl(2P3/2) and spin-orbitally excited Cl(2P1/2) atoms by REMPI technique. Also, the P+, PCl+, PCl+, and PCl+ photoions have been monitored non-resonantly in parallel with detection of REMPI-produced Cl+ ions. The speed distributions and speed-dependent anisotropy ± parameters β for all these particles have been determined by three-dimensional photofragment ion imaging technique. The β parameters are close to zero for all these particles. The relative yields of excited Cl(2P1/2) atoms for photodissociation of PCl3 is 0.49 0.03. The speed distributions of Cl(2P3/2) and Cl(2P1/2) atoms are bimodal. We explain the bimodal distributions as a result of competition between two REMPI channels. One channel is far-from-resonance one-photon photodissociation, the another channel is near-resonant two-photon ionisation followed by near-resonance one-photon photodissociation. ",
author = "Chichinin, {A. I.} and C. Maul and Gericke, {K. H.}",
note = "Publisher Copyright: {\textcopyright} 2020 Author(s). Copyright: Copyright 2020 Elsevier B.V., All rights reserved.; 2nd International Conference on Physics and Chemistry of Combustion and Processes in Extreme Environments, ComPhysChem 20-21 and 6th International Summer School on Modern Quantum Chemistry Methods in Applications ; Conference date: 26-07-2021 Through 30-07-2021",
year = "2020",
month = dec,
day = "8",
doi = "10.1063/5.0034239",
language = "English",
series = "AIP Conference Proceedings",
publisher = "American Institute of Physics Inc.",
editor = "Azyazov, {Valeriy N.} and Mebel, {Alexander M.}",
booktitle = "International Conference on Physics and Chemistry of Combustion and Processes in Extreme Environments, ComPhysChem 20-21 and VI International Summer School {"}Modern Quantum Chemistry Methods in Applications{"}",
}