Three-dimensional copper(II) carboxylates based on 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid)

Результат исследования: Научные публикации в периодических изданияхстатья

3 Цитирования (Scopus)

Аннотация

The homochiral coordination polymers [Cu4(CH3OH)(H2O)4(Hbtb)(S-mal)2]•4H2O and [Cu4(CH3OH)(H2O)4(Hbtb)(R-mal)2]•4H2O were synthesized by heating S- or R-malic acid (H3mal), 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid) (H3btb), and copper(II) acetate in an aqueous methanolic solution. The reaction with copper(II) nitrate in aqueous dioxane afforded the coordination framework [Cu6(C4H8O2)3(H2O)3(btb)4]•4C4H8O2•10H2O, which does not contain chiral ligands. The compositions and crystal structures of the new compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric and elemental analysis.

Язык оригиналаанглийский
Страницы (с-по)36-44
Число страниц9
ЖурналRussian Chemical Bulletin
Том67
Номер выпуска1
DOI
СостояниеОпубликовано - 1 янв 2018

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