Theoretical investigation of nitrogen gas hydrates outside of stability zone

Результат исследования: Научные публикации в периодических изданияхстатья по материалам конференции

Аннотация

Using a combination of Quasiharmonic Lattice Dynamic and Molecular Dynamic Simulation methods in conjunction with well developed statistical thermodynamics theory the thermodynamic properties of nitrogen gas hydrates has been calculated, with the main focus on the thermal expansion coefficient. It is shown that nitrogen gas hydrate displays larger value of the thermal expansion coefficient in comparison with hexagonal ice Ih and empty gas hydrate lattice, moreover this value is very close to one of the carbon dioxide and to other hydrates that have self-preservation effect. Exactly because of this difference in the thermal expansion coefficient it is possible to confirm existence of the self-preservation effect. The self-preservation effect can be used for creation of low-cost technology of hydrates storage and transportation technology applicable for many gas types.

Язык оригиналаанглийский
Номер статьи012049
Число страниц4
ЖурналJournal of Physics: Conference Series
Том1359
Номер выпуска1
DOI
СостояниеОпубликовано - 21 ноя 2019
Событие4th All-Russian Scientific Conference Thermophysics and Physical Hydrodynamics with the School for Young Scientists, TPH 2019 - Yalta, Crimea, Украина
Продолжительность: 15 сен 201922 сен 2019

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