The synthesis of new functionalized 1,3,5-triazine-based stable bi- and trinitroxides of the 2,5-dihydroimidazole series

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

New non-conjugated functionalized 2,5-dihydroimidazole-type bi- and trinitroxyl radicals are described. The synthesis of which was based on a nucleophilic substitution reaction between 2,4,6-trichloro-1,3,5-triazine or 2,4-dichloro-6-methoxy-1,3,5-triazine and spiro-fused 2,5-dihydroimidazole-type monoradicals bearing both a p-hydroxyaryl moiety at the C-4 atom of the heterocycle and a residue at the fourth position of the cyclohexane ring. The model tris-nitroxide with an unsubstituted cyclohexane unit was structurally characterized in the solid state.

Язык оригиналаанглийский
Страницы (с-по)359-374
Число страниц16
ЖурналArkivoc
Том2018
Номер выпуска5
DOI
СостояниеОпубликовано - 4 авг 2018

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