The {Re4} Tetrahedral Cyanometalate Cluster Anion [{Re43-CCN)4}(CN)12]8-with Inner (μ3-CCN)3-Ligands and Its Features in Coordination of Cu2+Cations

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

A reaction between ReI3 and KCN at elevated temperature led to the formation of the new cyanometalate cluster anion [{Re4(μ3-CCN)4}(CN)12]8- (1). The anion contains μ3-CCN3- ligands, which are stabilized by the coordination to the triangular faces of the tetrahedral {Re4} metallocluster in a μ3 mode. The compound crystallized as a potassium salt, and its crystal structure was determined by single-crystal X-ray diffraction analysis. It was shown that μ3-CCN3- ligands are ambidentate and can interact with transition-metal cations similarly to terminal CN groups, resulting in the polymer framework formation.

Язык оригиналаанглийский
Страницы (с-по)9710–9717
Число страниц8
ЖурналInorganic Chemistry
Том59
Номер выпуска14
DOI
СостояниеОпубликовано - 20 июл 2020

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