The first molybdenum oxo-iodide cluster – [mo4oi12]2–

Maxim A. Mikhaylov; Pavel A. Abramov; Igor N. Novozhilov; Maxim N. Sokolov

doi:10.1002/zaac.201800053

The first molybdenum oxo-iodide cluster – [mo₄oi₁₂]^2–

Maxim A. Mikhaylov, Pavel A. Abramov, Igor N. Novozhilov, Maxim N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

2 Цитирования (Scopus)

Аннотация

Reaction of Mo(CO)₆ with Bu₄NI and I₂ in diglyme yielded a new butterfly Mo^III cluster [Mo₄OI₁₂]^2–. The structure of tetraphen-ylphosphonium salt was determined by X-ray single crystal diffraction. Ph₄P⁺ and Bu₄N⁺ salts were further characterized by elemental analy-sis, mass spectrometry, energy-dispersive X-ray (EDX), IR, Raman, and UV/Vis spectroscopy and CVA studies. The cluster anion has a butterfly array of molybdenum atoms and can be represented as [Mo₄(μ₄-O)(μ₃-I)₂(μ₂-I₄)I₆]^2–.

Язык оригинала	английский
Страницы (с-по)	438-442
Число страниц	5
Журнал	Zeitschrift fur Anorganische und Allgemeine Chemie
Том	644
Номер выпуска	8-9
DOI	https://doi.org/10.1002/zaac.201800053
Состояние	Опубликовано - 17 мая 2018

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10.1002/zaac.201800053

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title = "The first molybdenum oxo-iodide cluster – [mo4oi12]2–",

abstract = "Reaction of Mo(CO)6 with Bu4NI and I2 in diglyme yielded a new butterfly MoIII cluster [Mo4OI12]2–. The structure of tetraphen-ylphosphonium salt was determined by X-ray single crystal diffraction. Ph4P+ and Bu4N+ salts were further characterized by elemental analy-sis, mass spectrometry, energy-dispersive X-ray (EDX), IR, Raman, and UV/Vis spectroscopy and CVA studies. The cluster anion has a butterfly array of molybdenum atoms and can be represented as [Mo4(μ4-O)(μ3-I)2(μ2-I4)I6]2–.",

keywords = "Butterfly-type core, Electrochemistry, Molybdenum, Molybdenum iodide cluster, Structure, Synthesis, ANTIBIOTICS, COMPLEXES, CELLULAR INTERNALIZATION, SULFONATE, CL, BR, LIGANDS, REDOX, TETRAHYDROFURAN",

author = "Mikhaylov, {Maxim A.} and Abramov, {Pavel A.} and Novozhilov, {Igor N.} and Sokolov, {Maxim N.}",

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The first molybdenum oxo-iodide cluster – [mo₄oi₁₂]^2–. / Mikhaylov, Maxim A.; Abramov, Pavel A.; Novozhilov, Igor N.; Sokolov, Maxim N.

В: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 644, № 8-9, 17.05.2018, стр. 438-442.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - The first molybdenum oxo-iodide cluster – [mo4oi12]2–

AU - Mikhaylov, Maxim A.

AU - Abramov, Pavel A.

AU - Novozhilov, Igor N.

AU - Sokolov, Maxim N.

PY - 2018/5/17

Y1 - 2018/5/17

N2 - Reaction of Mo(CO)6 with Bu4NI and I2 in diglyme yielded a new butterfly MoIII cluster [Mo4OI12]2–. The structure of tetraphen-ylphosphonium salt was determined by X-ray single crystal diffraction. Ph4P+ and Bu4N+ salts were further characterized by elemental analy-sis, mass spectrometry, energy-dispersive X-ray (EDX), IR, Raman, and UV/Vis spectroscopy and CVA studies. The cluster anion has a butterfly array of molybdenum atoms and can be represented as [Mo4(μ4-O)(μ3-I)2(μ2-I4)I6]2–.

AB - Reaction of Mo(CO)6 with Bu4NI and I2 in diglyme yielded a new butterfly MoIII cluster [Mo4OI12]2–. The structure of tetraphen-ylphosphonium salt was determined by X-ray single crystal diffraction. Ph4P+ and Bu4N+ salts were further characterized by elemental analy-sis, mass spectrometry, energy-dispersive X-ray (EDX), IR, Raman, and UV/Vis spectroscopy and CVA studies. The cluster anion has a butterfly array of molybdenum atoms and can be represented as [Mo4(μ4-O)(μ3-I)2(μ2-I4)I6]2–.

KW - Butterfly-type core

KW - Electrochemistry

KW - Molybdenum

KW - Molybdenum iodide cluster

KW - Structure

KW - Synthesis

KW - ANTIBIOTICS

KW - COMPLEXES

KW - CELLULAR INTERNALIZATION

KW - SULFONATE

KW - CL

KW - BR

KW - LIGANDS

KW - REDOX

KW - TETRAHYDROFURAN

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U2 - 10.1002/zaac.201800053

DO - 10.1002/zaac.201800053

M3 - Article

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VL - 644

SP - 438

EP - 442

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

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