Аннотация
Reaction of Mo(CO)6 with Bu4NI and I2 in diglyme yielded a new butterfly MoIII cluster [Mo4OI12]2–. The structure of tetraphen-ylphosphonium salt was determined by X-ray single crystal diffraction. Ph4P+ and Bu4N+ salts were further characterized by elemental analy-sis, mass spectrometry, energy-dispersive X-ray (EDX), IR, Raman, and UV/Vis spectroscopy and CVA studies. The cluster anion has a butterfly array of molybdenum atoms and can be represented as [Mo4(μ4-O)(μ3-I)2(μ2-I4)I6]2–.
Язык оригинала | английский |
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Страницы (с-по) | 438-442 |
Число страниц | 5 |
Журнал | Zeitschrift fur Anorganische und Allgemeine Chemie |
Том | 644 |
Номер выпуска | 8-9 |
DOI | |
Состояние | Опубликовано - 17 мая 2018 |