The first example of a dysprosium–zirconium chalcogenide complex

A. Yu Konokhova; M. Yu Afonin; T. S. Sukhikh; S. N. Konchenko

doi:10.1134/S0022476621050061

The first example of a dysprosium–zirconium chalcogenide complex

A. Yu Konokhova, M. Yu Afonin, T. S. Sukhikh, S. N. Konchenko

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

The synthesis approach based on the acid-base interaction is used to synthesize 4f/4d heterometallic chalcogenide compounds. By the interaction of the acidic hydrosulfide complex of zirconium [Cp^'₂Zr(SH)₂](Cp′ = η⁵-t-BuC₅H₄) with basic Cp^*₂Dy(allyl)] a heterometallic [Cp^'₂Zr(μ-S)(μ₃-S)DyCp^*₂]₂ complex is obtained, which is the first example of dysprosium–zirconium chalcogenide coordination clusters (1). The structure of the complex is determined by single crystal Xray diffraction. New crystalline modifications of the known sulfide complex of zirconium Cp^'₂Zr(μ-S)₂, being the decomposition product of [Cp^'₂Zr(SH)₂] in solution, are also structurally characterized.

Язык оригинала	английский
Страницы (с-по)	704-710
Число страниц	7
Журнал	Journal of Structural Chemistry
Том	62
Номер выпуска	5
DOI	https://doi.org/10.1134/S0022476621050061
Состояние	Опубликовано - мая 2021

Предметные области OECD FOS+WOS

2.05 ТЕХНОЛОГИЯ МАТЕРИАЛОВ
1.04 ХИМИЧЕСКИЕ НАУКИ

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title = "The first example of a dysprosium–zirconium chalcogenide complex",

abstract = "The synthesis approach based on the acid-base interaction is used to synthesize 4f/4d heterometallic chalcogenide compounds. By the interaction of the acidic hydrosulfide complex of zirconium [Cp'2Zr(SH)2](Cp′ = η5-t-BuC5H4) with basic Cp*2Dy(allyl)] a heterometallic [Cp'2Zr(μ-S)(μ3-S)DyCp*2]2 complex is obtained, which is the first example of dysprosium–zirconium chalcogenide coordination clusters (1). The structure of the complex is determined by single crystal Xray diffraction. New crystalline modifications of the known sulfide complex of zirconium Cp'2Zr(μ-S)2, being the decomposition product of [Cp'2Zr(SH)2] in solution, are also structurally characterized.",

keywords = "crystal structure, dysprosium, heterometal complexes, sulfur, zirconium",

author = "Konokhova, {A. Yu} and Afonin, {M. Yu} and Sukhikh, {T. S.} and Konchenko, {S. N.}",

note = "Funding Information: The work was supported by the Russian Science Foundation (grant No. 16-13-10294). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

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doi = "10.1134/S0022476621050061",

language = "English",

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The first example of a dysprosium–zirconium chalcogenide complex. / Konokhova, A. Yu; Afonin, M. Yu; Sukhikh, T. S. и др.

В: Journal of Structural Chemistry, Том 62, № 5, 05.2021, стр. 704-710.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - The first example of a dysprosium–zirconium chalcogenide complex

AU - Konokhova, A. Yu

AU - Afonin, M. Yu

AU - Sukhikh, T. S.

AU - Konchenko, S. N.

PY - 2021/5

Y1 - 2021/5

N2 - The synthesis approach based on the acid-base interaction is used to synthesize 4f/4d heterometallic chalcogenide compounds. By the interaction of the acidic hydrosulfide complex of zirconium [Cp'2Zr(SH)2](Cp′ = η5-t-BuC5H4) with basic Cp*2Dy(allyl)] a heterometallic [Cp'2Zr(μ-S)(μ3-S)DyCp*2]2 complex is obtained, which is the first example of dysprosium–zirconium chalcogenide coordination clusters (1). The structure of the complex is determined by single crystal Xray diffraction. New crystalline modifications of the known sulfide complex of zirconium Cp'2Zr(μ-S)2, being the decomposition product of [Cp'2Zr(SH)2] in solution, are also structurally characterized.

AB - The synthesis approach based on the acid-base interaction is used to synthesize 4f/4d heterometallic chalcogenide compounds. By the interaction of the acidic hydrosulfide complex of zirconium [Cp'2Zr(SH)2](Cp′ = η5-t-BuC5H4) with basic Cp*2Dy(allyl)] a heterometallic [Cp'2Zr(μ-S)(μ3-S)DyCp*2]2 complex is obtained, which is the first example of dysprosium–zirconium chalcogenide coordination clusters (1). The structure of the complex is determined by single crystal Xray diffraction. New crystalline modifications of the known sulfide complex of zirconium Cp'2Zr(μ-S)2, being the decomposition product of [Cp'2Zr(SH)2] in solution, are also structurally characterized.

KW - crystal structure

KW - dysprosium

KW - heterometal complexes

KW - sulfur

KW - zirconium

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JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

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The first example of a dysprosium–zirconium chalcogenide complex

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