The effect of amorphization on the molecular motion of the 2-methylimidazolate linkers in ZIF-8

Naoki Ogiwara; Daniil I. Kolokolov; Masaki Donoshita; Hirokazu Kobayashi; Satoshi Horike; Alexander G. Stepanov; Hiroshi Kitagawa

doi:10.1039/c9cc02673h

The effect of amorphization on the molecular motion of the 2-methylimidazolate linkers in ZIF-8

Naoki Ogiwara, Daniil I. Kolokolov, Masaki Donoshita, Hirokazu Kobayashi, Satoshi Horike, Alexander G. Stepanov, Hiroshi Kitagawa

Результат исследования: Научные публикации в периодических изданиях › статья

5 Цитирования (Scopus)

Аннотация

We investigated the effect of amorphization on the mobility of the 2-methylimidazolate linkers in ZIF-8. Solid-state ² H NMR studies revealed that amorphization significantly affects the mobility of the linkers, including the rotational angle and speed. Furthermore, a new intermediate librational mode appeared in amorphous ZIF-8.

Язык оригинала	английский
Страницы (с-по)	5906-5909
Число страниц	4
Журнал	Chemical Communications
Том	55
Номер выпуска	42
DOI	https://doi.org/10.1039/c9cc02673h
Состояние	Опубликовано - 25 мая 2019

Доступ к документу

10.1039/c9cc02673h

Link to publication in Scopus

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Цитировать

Ogiwara, N., Kolokolov, D. I., Donoshita, M., Kobayashi, H., Horike, S., Stepanov, A. G., & Kitagawa, H. (2019). The effect of amorphization on the molecular motion of the 2-methylimidazolate linkers in ZIF-8. Chemical Communications, 55(42), 5906-5909. https://doi.org/10.1039/c9cc02673h

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abstract = " We investigated the effect of amorphization on the mobility of the 2-methylimidazolate linkers in ZIF-8. Solid-state 2 H NMR studies revealed that amorphization significantly affects the mobility of the linkers, including the rotational angle and speed. Furthermore, a new intermediate librational mode appeared in amorphous ZIF-8. ",

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The effect of amorphization on the molecular motion of the 2-methylimidazolate linkers in ZIF-8. / Ogiwara, Naoki; Kolokolov, Daniil I.; Donoshita, Masaki; Kobayashi, Hirokazu; Horike, Satoshi; Stepanov, Alexander G.; Kitagawa, Hiroshi.

В: Chemical Communications, Том 55, № 42, 25.05.2019, стр. 5906-5909.

Результат исследования: Научные публикации в периодических изданиях › статья

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AU - Kolokolov, Daniil I.

AU - Donoshita, Masaki

AU - Kobayashi, Hirokazu

AU - Horike, Satoshi

AU - Stepanov, Alexander G.

AU - Kitagawa, Hiroshi

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