Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re                         
                        4
                                                 As                         
                        3
                                                 Q}                         
                        5+
                                                  (Q = S, Se) and {Re                         
                        4
                                                 As                         
                        2
                                                 S                         
                        2
                                                 }                         
                        6+

Aleksei S. Pronin; Yakov M. Gayfulin; Anton I. Smolentsev; Yuri V. Mironov

doi:10.1007/s10876-019-01566-z

Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re ₄ As ₃ Q} ⁵⁺ (Q = S, Se) and {Re ₄ As ₂ S ₂ } ⁶⁺

Aleksei S. Pronin, Yakov M. Gayfulin, Anton I. Smolentsev, Yuri V. Mironov

Лаборатория полиядерных координационных соединений ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья

1 Цитирования (Scopus)

Аннотация

A high-temperature reactions of equimolar amounts of ReI ₃ , As and S or Se with KCN following by recrystallization of the soluble products from water led to the formation of new cyanometallate cluster complexes K ₇ [{Re ₄ As ₃ S}(CN) ₁₂ ]·10H ₂ O (1) and K ₇ [{Re ₄ As ₃ Se}(CN) ₁₂ ]·9.5H ₂ O (2), respectively. Involvement of As ₂ S ₃ instead of the mixture of As and S resulted in the formation of a cluster complex K ₆ [{Re ₄ As ₂ S ₂ }(CN) ₁₂ ]·3.5H ₂ O (3). Crystal structures of the obtained compounds were investigated by the X-ray diffraction analysis. It was found that compounds 1–3 contain a new cubane cluster cores composed of the rhenium tetrahedron surrounded by the µ ₃ -As and µ ₃ -Q (Q = S, Se) ligands.

Язык оригинала	английский
Страницы (с-по)	1253-1257
Число страниц	5
Журнал	Journal of Cluster Science
Том	30
Номер выпуска	5
DOI	https://doi.org/10.1007/s10876-019-01566-z
Состояние	Опубликовано - 1 сен 2019

Доступ к документу

10.1007/s10876-019-01566-z

Link to publication in Scopus

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Цитировать

Pronin, A. S., Gayfulin, Y. M., Smolentsev, A. I., & Mironov, Y. V. (2019). Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re ₄ As ₃ Q} ⁵⁺ (Q = S, Se) and {Re ₄ As ₂ S ₂ } ⁶⁺. Journal of Cluster Science, 30(5), 1253-1257. https://doi.org/10.1007/s10876-019-01566-z

Pronin, Aleksei S. ; Gayfulin, Yakov M. ; Smolentsev, Anton I. ; Mironov, Yuri V. / Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re ₄ As ₃ Q} ⁵⁺ (Q = S, Se) and {Re ₄ As ₂ S ₂ } ⁶⁺. В: Journal of Cluster Science. 2019 ; Том 30, № 5. стр. 1253-1257.

@article{b4fd2504669c400fbb3859273279fed1,

title = "Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re 4 As 3 Q} 5+ (Q = S, Se) and {Re 4 As 2 S 2 } 6+",

abstract = " A high-temperature reactions of equimolar amounts of ReI 3 , As and S or Se with KCN following by recrystallization of the soluble products from water led to the formation of new cyanometallate cluster complexes K 7 [{Re 4 As 3 S}(CN) 12 ]·10H 2 O (1) and K 7 [{Re 4 As 3 Se}(CN) 12 ]·9.5H 2 O (2), respectively. Involvement of As 2 S 3 instead of the mixture of As and S resulted in the formation of a cluster complex K 6 [{Re 4 As 2 S 2 }(CN) 12 ]·3.5H 2 O (3). Crystal structures of the obtained compounds were investigated by the X-ray diffraction analysis. It was found that compounds 1–3 contain a new cubane cluster cores composed of the rhenium tetrahedron surrounded by the µ 3 -As and µ 3 -Q (Q = S, Se) ligands. ",

keywords = "Arsenic, Chalcogen, Crystal structure, Cyanometallate, Heteroligand cluster",

author = "Pronin, {Aleksei S.} and Gayfulin, {Yakov M.} and Smolentsev, {Anton I.} and Mironov, {Yuri V.}",

year = "2019",

month = sep,

day = "1",

doi = "10.1007/s10876-019-01566-z",

language = "English",

volume = "30",

pages = "1253--1257",

journal = "Journal of Cluster Science",

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Pronin, AS, Gayfulin, YM, Smolentsev, AI & Mironov, YV 2019, 'Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re ₄ As ₃ Q} ⁵⁺ (Q = S, Se) and {Re ₄ As ₂ S ₂ } ⁶⁺', Journal of Cluster Science, том. 30, № 5, стр. 1253-1257. https://doi.org/10.1007/s10876-019-01566-z

Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re ₄ As ₃ Q} ⁵⁺ (Q = S, Se) and {Re ₄ As ₂ S ₂ } ⁶⁺. / Pronin, Aleksei S.; Gayfulin, Yakov M.; Smolentsev, Anton I.; Mironov, Yuri V.

В: Journal of Cluster Science, Том 30, № 5, 01.09.2019, стр. 1253-1257.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re 4 As 3 Q} 5+ (Q = S, Se) and {Re 4 As 2 S 2 } 6+

AU - Pronin, Aleksei S.

AU - Gayfulin, Yakov M.

AU - Smolentsev, Anton I.

AU - Mironov, Yuri V.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - 3 7 [{Re 4 As 3 S}(CN) 12 ]·10H 2 O (1) and K 7 [{Re 4 As 3 Se}(CN) 12 ]·9.5H 2 2 S 3 6 [{Re 4 As 2 S 2 }(CN) 12 ]·3.5H 2 3 -As and µ 3 A high-temperature reactions of equimolar amounts of ReI , As and S or Se with KCN following by recrystallization of the soluble products from water led to the formation of new cyanometallate cluster complexes K O (2), respectively. Involvement of As instead of the mixture of As and S resulted in the formation of a cluster complex K O (3). Crystal structures of the obtained compounds were investigated by the X-ray diffraction analysis. It was found that compounds 1–3 contain a new cubane cluster cores composed of the rhenium tetrahedron surrounded by the µ -Q (Q = S, Se) ligands.

AB - A high-temperature reactions of equimolar amounts of ReI 3 , As and S or Se with KCN following by recrystallization of the soluble products from water led to the formation of new cyanometallate cluster complexes K 7 [{Re 4 As 3 S}(CN) 12 ]·10H 2 O (1) and K 7 [{Re 4 As 3 Se}(CN) 12 ]·9.5H 2 O (2), respectively. Involvement of As 2 S 3 instead of the mixture of As and S resulted in the formation of a cluster complex K 6 [{Re 4 As 2 S 2 }(CN) 12 ]·3.5H 2 O (3). Crystal structures of the obtained compounds were investigated by the X-ray diffraction analysis. It was found that compounds 1–3 contain a new cubane cluster cores composed of the rhenium tetrahedron surrounded by the µ 3 -As and µ 3 -Q (Q = S, Se) ligands.

KW - Arsenic

KW - Chalcogen

KW - Crystal structure

KW - Cyanometallate

KW - Heteroligand cluster

UR - http://www.scopus.com/inward/record.url?scp=85064889082&partnerID=8YFLogxK

U2 - 10.1007/s10876-019-01566-z

DO - 10.1007/s10876-019-01566-z

M3 - Article

AN - SCOPUS:85064889082

VL - 30

SP - 1253

EP - 1257

JO - Journal of Cluster Science

JF - Journal of Cluster Science

SN - 1040-7278

IS - 5

ER -

Pronin AS, Gayfulin YM, Smolentsev AI , Mironov YV. Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re ₄ As ₃ Q} ⁵⁺ (Q = S, Se) and {Re ₄ As ₂ S ₂ } ⁶⁺. Journal of Cluster Science. 2019 Сент. 1;30(5):1253-1257. https://doi.org/10.1007/s10876-019-01566-z