Аннотация
Complexes (HTMP)4[Bi4I16] · 2H2O · 2(CH3)2CO (I) and (HTMP)3[Bi5I18] · 5THF (II) have been synthesized by the reactions of BiI3 and 2,3,5,6-tetramethylpyrazine (TMP) in acetone and tetrahydrofuran (THF), respectively. The crystal structures of both compounds were determined by X-ray diffraction analysis (СIF files CCDC nos. 1817306 (I) and 1817307 (II)). In both cases, the complexes in the solid state feature supramolecular contacts between the π systems of the cations and iodide ligands of the anions.
Язык оригинала | английский |
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Страницы (с-по) | 772-778 |
Число страниц | 7 |
Журнал | Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
Том | 44 |
Номер выпуска | 12 |
DOI | |
Состояние | Опубликовано - 1 дек 2018 |