Tetra- and Pentanuclear Iodobismuthates with the Cation Based on 2,3,5,6-Tetramethylpyrazine: Syntheses and Crystal Structures

A. N. Usoltsev; S. A. Adonin; P. A. Abramov; M. N. Sokolov; V. P. Fedin

doi:10.1134/S1070328418120102

Tetra- and Pentanuclear Iodobismuthates with the Cation Based on 2,3,5,6-Tetramethylpyrazine: Syntheses and Crystal Structures

A. N. Usoltsev, S. A. Adonin, P. A. Abramov, M. N. Sokolov, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

2 Цитирования (Scopus)

Аннотация

Complexes (HTMP)₄[Bi₄I₁₆] · 2H₂O · 2(CH₃)₂CO (I) and (HTMP)₃[Bi₅I₁₈] · 5THF (II) have been synthesized by the reactions of BiI₃ and 2,3,5,6-tetramethylpyrazine (TMP) in acetone and tetrahydrofuran (THF), respectively. The crystal structures of both compounds were determined by X-ray diffraction analysis (СIF files CCDC nos. 1817306 (I) and 1817307 (II)). In both cases, the complexes in the solid state feature supramolecular contacts between the π systems of the cations and iodide ligands of the anions.

Язык оригинала	английский
Страницы (с-по)	772-778
Число страниц	7
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	44
Номер выпуска	12
DOI	https://doi.org/10.1134/S1070328418120102
Состояние	Опубликовано - 1 дек. 2018

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10.1134/S1070328418120102

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abstract = "Complexes (HTMP)4[Bi4I16] · 2H2O · 2(CH3)2CO (I) and (HTMP)3[Bi5I18] · 5THF (II) have been synthesized by the reactions of BiI3 and 2,3,5,6-tetramethylpyrazine (TMP) in acetone and tetrahydrofuran (THF), respectively. The crystal structures of both compounds were determined by X-ray diffraction analysis (СIF files CCDC nos. 1817306 (I) and 1817307 (II)). In both cases, the complexes in the solid state feature supramolecular contacts between the π systems of the cations and iodide ligands of the anions.",

keywords = "bismuth, halide complexes, supramolecular contacts, tetramethylpyrazine, X-ray diffraction analysis, COMPLEXES, OPTICAL-PROPERTIES, SOLID-STATE, BISMUTH IODIDE",

author = "Usoltsev, {A. N.} and Adonin, {S. A.} and Abramov, {P. A.} and Sokolov, {M. N.} and Fedin, {V. P.}",

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doi = "10.1134/S1070328418120102",

language = "English",

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Tetra- and Pentanuclear Iodobismuthates with the Cation Based on 2,3,5,6-Tetramethylpyrazine : Syntheses and Crystal Structures. / Usoltsev, A. N.; Adonin, S. A.; Abramov, P. A. и др.

В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 44, № 12, 01.12.2018, стр. 772-778.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Tetra- and Pentanuclear Iodobismuthates with the Cation Based on 2,3,5,6-Tetramethylpyrazine

T2 - Syntheses and Crystal Structures

AU - Usoltsev, A. N.

AU - Adonin, S. A.

AU - Abramov, P. A.

AU - Sokolov, M. N.

AU - Fedin, V. P.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - Complexes (HTMP)4[Bi4I16] · 2H2O · 2(CH3)2CO (I) and (HTMP)3[Bi5I18] · 5THF (II) have been synthesized by the reactions of BiI3 and 2,3,5,6-tetramethylpyrazine (TMP) in acetone and tetrahydrofuran (THF), respectively. The crystal structures of both compounds were determined by X-ray diffraction analysis (СIF files CCDC nos. 1817306 (I) and 1817307 (II)). In both cases, the complexes in the solid state feature supramolecular contacts between the π systems of the cations and iodide ligands of the anions.

AB - Complexes (HTMP)4[Bi4I16] · 2H2O · 2(CH3)2CO (I) and (HTMP)3[Bi5I18] · 5THF (II) have been synthesized by the reactions of BiI3 and 2,3,5,6-tetramethylpyrazine (TMP) in acetone and tetrahydrofuran (THF), respectively. The crystal structures of both compounds were determined by X-ray diffraction analysis (СIF files CCDC nos. 1817306 (I) and 1817307 (II)). In both cases, the complexes in the solid state feature supramolecular contacts between the π systems of the cations and iodide ligands of the anions.

KW - bismuth

KW - halide complexes

KW - supramolecular contacts

KW - tetramethylpyrazine

KW - X-ray diffraction analysis

KW - COMPLEXES

KW - OPTICAL-PROPERTIES

KW - SOLID-STATE

KW - BISMUTH IODIDE

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U2 - 10.1134/S1070328418120102

DO - 10.1134/S1070328418120102

M3 - Article

AN - SCOPUS:85060273284

VL - 44

SP - 772

EP - 778

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

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