@article{d65e71d5e332484ea424ed919e030afd,
title = "Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−",
abstract = "Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n− (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.",
keywords = "cluster compounds, electronic structure, EXAFS, heterometallic complexes, structure, MOLYBDENUM, OCTAHEDRAL CLUSTERS, X-RAY",
author = "Muravieva, {Viktoria K.} and Gayfulin, {Yakov M.} and Carmelo Prestipino and Pierric Lemoine and Ryzhikov, {Maxim R.} and Yanshole, {Vadim V.} and St{\'e}phane Cordier and Naumov, {Nikolay G.}",
note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",
year = "2019",
month = nov,
day = "27",
doi = "10.1002/chem.201903321",
language = "English",
volume = "25",
pages = "15040--15045",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "66",
}