Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−

Viktoria K. Muravieva; Yakov M. Gayfulin; Carmelo Prestipino; Pierric Lemoine; Maxim R. Ryzhikov; Vadim V. Yanshole; Stéphane Cordier; Nikolay G. Naumov

doi:10.1002/chem.201903321

Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re_6−xMo_xSe₈(CN)₆]ⁿ⁻

Viktoria K. Muravieva, Yakov M. Gayfulin, Carmelo Prestipino, Pierric Lemoine, Maxim R. Ryzhikov, Vadim V. Yanshole, Stéphane Cordier, Nikolay G. Naumov

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)₆ octahedral clusters. The discrete anionic clusters [Re_6-xMo_xSe₈(CN)₆]ⁿ⁻ (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.

Язык оригинала	английский
Страницы (с-по)	15040-15045
Число страниц	6
Журнал	Chemistry - A European Journal
Том	25
Номер выпуска	66
DOI	https://doi.org/10.1002/chem.201903321
Состояние	Опубликовано - 27 ноя 2019

Доступ к документу

10.1002/chem.201903321

Link to publication in Scopus

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Цитировать

Muravieva, V. K., Gayfulin, Y. M., Prestipino, C., Lemoine, P., Ryzhikov, M. R., Yanshole, V. V., Cordier, S., & Naumov, N. G. (2019). Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re_6−xMo_xSe₈(CN)₆]ⁿ⁻. Chemistry - A European Journal, 25(66), 15040-15045. https://doi.org/10.1002/chem.201903321

Muravieva, Viktoria K. ; Gayfulin, Yakov M. ; Prestipino, Carmelo ; Lemoine, Pierric ; Ryzhikov, Maxim R. ; Yanshole, Vadim V. ; Cordier, Stéphane ; Naumov, Nikolay G. / Tailoring Heterometallic Cluster Functional Building Blocks : Synthesis, Separation, Structural and DFT Studies of [Re_6−xMo_xSe₈(CN)₆]ⁿ⁻. В: Chemistry - A European Journal. 2019 ; Том 25, № 66. стр. 15040-15045.

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title = "Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−",

abstract = "Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n− (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.",

keywords = "cluster compounds, electronic structure, EXAFS, heterometallic complexes, structure, MOLYBDENUM, OCTAHEDRAL CLUSTERS, X-RAY",

author = "Muravieva, {Viktoria K.} and Gayfulin, {Yakov M.} and Carmelo Prestipino and Pierric Lemoine and Ryzhikov, {Maxim R.} and Yanshole, {Vadim V.} and St{\'e}phane Cordier and Naumov, {Nikolay G.}",

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year = "2019",

month = nov,

day = "27",

doi = "10.1002/chem.201903321",

language = "English",

volume = "25",

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journal = "Chemistry - A European Journal",

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Tailoring Heterometallic Cluster Functional Building Blocks : Synthesis, Separation, Structural and DFT Studies of [Re_6−xMo_xSe₈(CN)₆]ⁿ⁻. / Muravieva, Viktoria K.; Gayfulin, Yakov M.; Prestipino, Carmelo; Lemoine, Pierric; Ryzhikov, Maxim R.; Yanshole, Vadim V.; Cordier, Stéphane; Naumov, Nikolay G.

В: Chemistry - A European Journal, Том 25, № 66, 27.11.2019, стр. 15040-15045.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Tailoring Heterometallic Cluster Functional Building Blocks

T2 - Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−

AU - Muravieva, Viktoria K.

AU - Gayfulin, Yakov M.

AU - Prestipino, Carmelo

AU - Lemoine, Pierric

AU - Ryzhikov, Maxim R.

AU - Yanshole, Vadim V.

AU - Cordier, Stéphane

AU - Naumov, Nikolay G.

PY - 2019/11/27

Y1 - 2019/11/27

N2 - Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n− (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.

AB - Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n− (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.

KW - cluster compounds

KW - electronic structure

KW - EXAFS

KW - heterometallic complexes

KW - structure

KW - MOLYBDENUM

KW - OCTAHEDRAL CLUSTERS

KW - X-RAY

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U2 - 10.1002/chem.201903321

DO - 10.1002/chem.201903321

M3 - Article

C2 - 31468567

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

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