Synthesis, Structure, and Spectral Studies of the (Et4N)4[Nb2O2(C2O4)4(µ-C2O4)] Complex

A. A. Shmakova; P. A. Abramov; M. N. Sokolov

doi:10.1134/S0022476619070084

Synthesis, Structure, and Spectral Studies of the (Et₄N)₄[Nb₂O₂(C₂O₄)₄(µ-C₂O₄)] Complex

A. A. Shmakova, P. A. Abramov, M. N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

The bis(oxalate) complex of niobium (NH₄)[NbO(C₂O₄)₂(H₂O)₂]·3H₂O can be dissolved in DMF on heating. Ether diffusion into this solution in the presence of Et₄NBr leads to the formation of colorless crystals of (Et₄N)₄[Nb₂O₂(C₂O₄)₄(μ-C₂O₄)] (1). The characterization of the obtained compound by single crystal and powder XRD, IR and Raman spectroscopy, and elemental analysis allows to clarify processes occurring with the bis(oxalate) niobium complex in aqueous solutions.

Язык оригинала	английский
Страницы (с-по)	1080-1085
Число страниц	6
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	7
DOI	https://doi.org/10.1134/S0022476619070084
Состояние	Опубликовано - 1 июл 2019

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10.1134/S0022476619070084

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title = "Synthesis, Structure, and Spectral Studies of the (Et4N)4[Nb2O2(C2O4)4(µ-C2O4)] Complex",

abstract = "The bis(oxalate) complex of niobium (NH4)[NbO(C2O4)2(H2O)2]·3H2O can be dissolved in DMF on heating. Ether diffusion into this solution in the presence of Et4NBr leads to the formation of colorless crystals of (Et4N)4[Nb2O2(C2O4)4(μ-C2O4)] (1). The characterization of the obtained compound by single crystal and powder XRD, IR and Raman spectroscopy, and elemental analysis allows to clarify processes occurring with the bis(oxalate) niobium complex in aqueous solutions.",

keywords = "crystal structure, niobium, oxalate complex, ACIDS, CRYSTAL-STRUCTURE, TANTALUM, WATER-SOLUBLE COMPLEXES, NIOBIUM COLUMBIUM",

author = "Shmakova, {A. A.} and Abramov, {P. A.} and Sokolov, {M. N.}",

year = "2019",

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Synthesis, Structure, and Spectral Studies of the (Et₄N)₄[Nb₂O₂(C₂O₄)₄(µ-C₂O₄)] Complex. / Shmakova, A. A.; Abramov, P. A.; Sokolov, M. N.

В: Journal of Structural Chemistry, Том 60, № 7, 01.07.2019, стр. 1080-1085.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Synthesis, Structure, and Spectral Studies of the (Et4N)4[Nb2O2(C2O4)4(µ-C2O4)] Complex

AU - Shmakova, A. A.

AU - Abramov, P. A.

AU - Sokolov, M. N.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - The bis(oxalate) complex of niobium (NH4)[NbO(C2O4)2(H2O)2]·3H2O can be dissolved in DMF on heating. Ether diffusion into this solution in the presence of Et4NBr leads to the formation of colorless crystals of (Et4N)4[Nb2O2(C2O4)4(μ-C2O4)] (1). The characterization of the obtained compound by single crystal and powder XRD, IR and Raman spectroscopy, and elemental analysis allows to clarify processes occurring with the bis(oxalate) niobium complex in aqueous solutions.

AB - The bis(oxalate) complex of niobium (NH4)[NbO(C2O4)2(H2O)2]·3H2O can be dissolved in DMF on heating. Ether diffusion into this solution in the presence of Et4NBr leads to the formation of colorless crystals of (Et4N)4[Nb2O2(C2O4)4(μ-C2O4)] (1). The characterization of the obtained compound by single crystal and powder XRD, IR and Raman spectroscopy, and elemental analysis allows to clarify processes occurring with the bis(oxalate) niobium complex in aqueous solutions.

KW - crystal structure

KW - niobium

KW - oxalate complex

KW - ACIDS

KW - CRYSTAL-STRUCTURE

KW - TANTALUM

KW - WATER-SOLUBLE COMPLEXES

KW - NIOBIUM COLUMBIUM

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DO - 10.1134/S0022476619070084

M3 - Article

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JO - Journal of Structural Chemistry

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