Synthesis, Structure, and Spectral Studies of the (Et4N)4[Nb2O2(C2O4)4(µ-C2O4)] Complex

A. A. Shmakova; P. A. Abramov; M. N. Sokolov

doi:10.1134/S0022476619070084

Synthesis, Structure, and Spectral Studies of the (Et₄N)₄[Nb₂O₂(C₂O₄)₄(µ-C₂O₄)] Complex

A. A. Shmakova, P. A. Abramov, M. N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

The bis(oxalate) complex of niobium (NH₄)[NbO(C₂O₄)₂(H₂O)₂]·3H₂O can be dissolved in DMF on heating. Ether diffusion into this solution in the presence of Et₄NBr leads to the formation of colorless crystals of (Et₄N)₄[Nb₂O₂(C₂O₄)₄(μ-C₂O₄)] (1). The characterization of the obtained compound by single crystal and powder XRD, IR and Raman spectroscopy, and elemental analysis allows to clarify processes occurring with the bis(oxalate) niobium complex in aqueous solutions.

Язык оригинала	английский
Страницы (с-по)	1080-1085
Число страниц	6
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	7
DOI	https://doi.org/10.1134/S0022476619070084
Состояние	Опубликовано - 1 июл 2019

Доступ к документу

10.1134/S0022476619070084

Link to publication in Scopus

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Цитировать

Shmakova, A. A., Abramov, P. A., & Sokolov, M. N. (2019). Synthesis, Structure, and Spectral Studies of the (Et₄N)₄[Nb₂O₂(C₂O₄)₄(µ-C₂O₄)] Complex. Journal of Structural Chemistry, 60(7), 1080-1085. https://doi.org/10.1134/S0022476619070084

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abstract = "The bis(oxalate) complex of niobium (NH4)[NbO(C2O4)2(H2O)2]·3H2O can be dissolved in DMF on heating. Ether diffusion into this solution in the presence of Et4NBr leads to the formation of colorless crystals of (Et4N)4[Nb2O2(C2O4)4(μ-C2O4)] (1). The characterization of the obtained compound by single crystal and powder XRD, IR and Raman spectroscopy, and elemental analysis allows to clarify processes occurring with the bis(oxalate) niobium complex in aqueous solutions.",

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AU - Abramov, P. A.

AU - Sokolov, M. N.

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AB - The bis(oxalate) complex of niobium (NH4)[NbO(C2O4)2(H2O)2]·3H2O can be dissolved in DMF on heating. Ether diffusion into this solution in the presence of Et4NBr leads to the formation of colorless crystals of (Et4N)4[Nb2O2(C2O4)4(μ-C2O4)] (1). The characterization of the obtained compound by single crystal and powder XRD, IR and Raman spectroscopy, and elemental analysis allows to clarify processes occurring with the bis(oxalate) niobium complex in aqueous solutions.

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KW - oxalate complex

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KW - CRYSTAL-STRUCTURE

KW - TANTALUM

KW - WATER-SOLUBLE COMPLEXES

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