Synthesis, structure and properties of (NH4)2[RuNO(NO2)4OH] and NH4[RuNO(L)(NO2)3OH] (L=NH3, Py)

Gennadiy A. Kostin; Alexander O. Borodin; Natalia V. Kuratieva; Artem A. Mikhailov; Pavel E. Plusnin

doi:10.1016/j.molstruc.2018.08.105

Synthesis, structure and properties of (NH₄)₂[RuNO(NO₂)₄OH] and NH₄[RuNO(L)(NO₂)₃OH] (L=NH₃, Py)

Gennadiy A. Kostin, Alexander O. Borodin, Natalia V. Kuratieva, Artem A. Mikhailov, Pavel E. Plusnin

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

The ammonium salt (NH₄)₂[RuNO(NO₂)₄OH] was prepared, characterized by thermogravimetric analysis, IR spectroscopy and its molecular and crystal structures were determined. Heating of the salt was investigated in organic solvents (pyridine and acetonitrile) using ¹⁵N-NMR spectroscopy and the reaction led to the preparation of the [RuNO(NO₂)₃(Py)OH]^- anion with good yield (60%). Crystal structures of the two products (NH₄)[RuNO(NO₂)₃(Py)OH] and NH₄[RuNO(NO₂)₃(NH₃)OH] were determined. Both (NH₄)₂[RuNO(NO₂)₄OH] and (NH₄)[RuNO(NO₂)₃(Py)OH] underwent photo-induced (445 nm) linkage isomerization (RueNO to Ru–ON) but the population of the metastable isomer did not exceed 5–7%.

Язык оригинала	английский
Страницы (с-по)	402-407
Число страниц	6
Журнал	Journal of Molecular Structure
Том	1176
DOI	https://doi.org/10.1016/j.molstruc.2018.08.105
Состояние	Опубликовано - 15 янв 2019

Доступ к документу

10.1016/j.molstruc.2018.08.105

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Kostin, G. A., Borodin, A. O., Kuratieva, N. V., Mikhailov, A. A., & Plusnin, P. E. (2019). Synthesis, structure and properties of (NH₄)₂[RuNO(NO₂)₄OH] and NH₄[RuNO(L)(NO₂)₃OH] (L=NH₃, Py). Journal of Molecular Structure, 1176, 402-407. https://doi.org/10.1016/j.molstruc.2018.08.105

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title = "Synthesis, structure and properties of (NH4)2[RuNO(NO2)4OH] and NH4[RuNO(L)(NO2)3OH] (L=NH3, Py)",

abstract = "The ammonium salt (NH4)2[RuNO(NO2)4OH] was prepared, characterized by thermogravimetric analysis, IR spectroscopy and its molecular and crystal structures were determined. Heating of the salt was investigated in organic solvents (pyridine and acetonitrile) using 15N-NMR spectroscopy and the reaction led to the preparation of the [RuNO(NO2)3(Py)OH]- anion with good yield (60%). Crystal structures of the two products (NH4)[RuNO(NO2)3(Py)OH] and NH4[RuNO(NO2)3(NH3)OH] were determined. Both (NH4)2[RuNO(NO2)4OH] and (NH4)[RuNO(NO2)3(Py)OH] underwent photo-induced (445 nm) linkage isomerization (RueNO to Ru–ON) but the population of the metastable isomer did not exceed 5–7%.",

keywords = "Crystal structure, Isomerization, Nitro complexes, Pyridine, Ruthenium nitrosyl, NO, SUBSTITUTION, RU, REACTIVITY, RUTHENIUM NITROSYL, NITROSYL COMPLEXES, LIGANDS, CHEMISTRY, NITRITE, BIOLOGICAL-PROPERTIES",

author = "Kostin, {Gennadiy A.} and Borodin, {Alexander O.} and Kuratieva, {Natalia V.} and Mikhailov, {Artem A.} and Plusnin, {Pavel E.}",

year = "2019",

month = jan,

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doi = "10.1016/j.molstruc.2018.08.105",

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Synthesis, structure and properties of (NH₄)₂[RuNO(NO₂)₄OH] and NH₄[RuNO(L)(NO₂)₃OH] (L=NH₃, Py). / Kostin, Gennadiy A.; Borodin, Alexander O.; Kuratieva, Natalia V.; Mikhailov, Artem A.; Plusnin, Pavel E.

В: Journal of Molecular Structure, Том 1176, 15.01.2019, стр. 402-407.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Synthesis, structure and properties of (NH4)2[RuNO(NO2)4OH] and NH4[RuNO(L)(NO2)3OH] (L=NH3, Py)

AU - Kostin, Gennadiy A.

AU - Borodin, Alexander O.

AU - Kuratieva, Natalia V.

AU - Mikhailov, Artem A.

AU - Plusnin, Pavel E.

PY - 2019/1/15

Y1 - 2019/1/15

N2 - The ammonium salt (NH4)2[RuNO(NO2)4OH] was prepared, characterized by thermogravimetric analysis, IR spectroscopy and its molecular and crystal structures were determined. Heating of the salt was investigated in organic solvents (pyridine and acetonitrile) using 15N-NMR spectroscopy and the reaction led to the preparation of the [RuNO(NO2)3(Py)OH]- anion with good yield (60%). Crystal structures of the two products (NH4)[RuNO(NO2)3(Py)OH] and NH4[RuNO(NO2)3(NH3)OH] were determined. Both (NH4)2[RuNO(NO2)4OH] and (NH4)[RuNO(NO2)3(Py)OH] underwent photo-induced (445 nm) linkage isomerization (RueNO to Ru–ON) but the population of the metastable isomer did not exceed 5–7%.

AB - The ammonium salt (NH4)2[RuNO(NO2)4OH] was prepared, characterized by thermogravimetric analysis, IR spectroscopy and its molecular and crystal structures were determined. Heating of the salt was investigated in organic solvents (pyridine and acetonitrile) using 15N-NMR spectroscopy and the reaction led to the preparation of the [RuNO(NO2)3(Py)OH]- anion with good yield (60%). Crystal structures of the two products (NH4)[RuNO(NO2)3(Py)OH] and NH4[RuNO(NO2)3(NH3)OH] were determined. Both (NH4)2[RuNO(NO2)4OH] and (NH4)[RuNO(NO2)3(Py)OH] underwent photo-induced (445 nm) linkage isomerization (RueNO to Ru–ON) but the population of the metastable isomer did not exceed 5–7%.

KW - Crystal structure

KW - Isomerization

KW - Nitro complexes

KW - Pyridine

KW - Ruthenium nitrosyl

KW - NO

KW - SUBSTITUTION

KW - RU

KW - REACTIVITY

KW - RUTHENIUM NITROSYL

KW - NITROSYL COMPLEXES

KW - LIGANDS

KW - CHEMISTRY

KW - NITRITE

KW - BIOLOGICAL-PROPERTIES

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U2 - 10.1016/j.molstruc.2018.08.105

DO - 10.1016/j.molstruc.2018.08.105

M3 - Article

AN - SCOPUS:85053770207

VL - 1176

SP - 402

EP - 407

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

ER -