Synthesis, Structure and Magnetic Properties of Copper(II) Complexes of Diphenyl-(1-propylbenzimidazol-2-yl)methanol

Anatolii S. Burlov; Yurii V. Koshchienko; Valery G. Vlasenko; Artem S. Bogomyakov; Alexandra A. Kolodina; Yan V. Zubavichus; Vladimir A. Lazarenko; Victor N. Khrustalev

doi:10.1002/slct.201901186

Synthesis, Structure and Magnetic Properties of Copper(II) Complexes of Diphenyl-(1-propylbenzimidazol-2-yl)methanol

Anatolii S. Burlov, Yurii V. Koshchienko, Valery G. Vlasenko, Artem S. Bogomyakov, Alexandra A. Kolodina, Yan V. Zubavichus, Vladimir A. Lazarenko, Victor N. Khrustalev

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

Two types of binuclear copper complexes [LCuN₃]₂ and [LCuNO₃]₂.of bidentate ligand - diphenyl-(1-propylbenzimidazol-2-yl)methanol (HL) in the 4:1 ratio were synthesized. The crystal structure of copper complexes shows a centrosymmetric dimeric binuclear complex with two Cu²⁺ cations bridged by two oxygen atoms from two organic ligands. In the complexes, a very strong antiferromagnetic exchange interaction between copper atoms is observed.

Язык оригинала	английский
Страницы (с-по)	8652-8654
Число страниц	3
Журнал	ChemistrySelect
Том	4
Номер выпуска	29
DOI	https://doi.org/10.1002/slct.201901186
Состояние	Опубликовано - 2019
Опубликовано для внешнего пользования	Да

Доступ к документу

10.1002/slct.201901186

Link to publication in Scopus

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title = "Synthesis, Structure and Magnetic Properties of Copper(II) Complexes of Diphenyl-(1-propylbenzimidazol-2-yl)methanol",

abstract = "Two types of binuclear copper complexes [LCuN3]2 and [LCuNO3]2.of bidentate ligand - diphenyl-(1-propylbenzimidazol-2-yl)methanol (HL) in the 4:1 ratio were synthesized. The crystal structure of copper complexes shows a centrosymmetric dimeric binuclear complex with two Cu2+ cations bridged by two oxygen atoms from two organic ligands. In the complexes, a very strong antiferromagnetic exchange interaction between copper atoms is observed.",

keywords = "antiferromagnetic exchange interaction, benzimidazole, binuclear copper complex, X-ray diffraction, CRYSTAL-STRUCTURE",

author = "Burlov, {Anatolii S.} and Koshchienko, {Yurii V.} and Vlasenko, {Valery G.} and Bogomyakov, {Artem S.} and Kolodina, {Alexandra A.} and Zubavichus, {Yan V.} and Lazarenko, {Vladimir A.} and Khrustalev, {Victor N.}",

year = "2019",

doi = "10.1002/slct.201901186",

language = "English",

volume = "4",

pages = "8652--8654",

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publisher = "Wiley-Blackwell",

number = "29",

}

Synthesis, Structure and Magnetic Properties of Copper(II) Complexes of Diphenyl-(1-propylbenzimidazol-2-yl)methanol. / Burlov, Anatolii S.; Koshchienko, Yurii V.; Vlasenko, Valery G.; Bogomyakov, Artem S.; Kolodina, Alexandra A.; Zubavichus, Yan V.; Lazarenko, Vladimir A.; Khrustalev, Victor N.

В: ChemistrySelect, Том 4, № 29, 2019, стр. 8652-8654.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Synthesis, Structure and Magnetic Properties of Copper(II) Complexes of Diphenyl-(1-propylbenzimidazol-2-yl)methanol

AU - Burlov, Anatolii S.

AU - Koshchienko, Yurii V.

AU - Vlasenko, Valery G.

AU - Bogomyakov, Artem S.

AU - Kolodina, Alexandra A.

AU - Zubavichus, Yan V.

AU - Lazarenko, Vladimir A.

AU - Khrustalev, Victor N.

PY - 2019

Y1 - 2019

N2 - Two types of binuclear copper complexes [LCuN3]2 and [LCuNO3]2.of bidentate ligand - diphenyl-(1-propylbenzimidazol-2-yl)methanol (HL) in the 4:1 ratio were synthesized. The crystal structure of copper complexes shows a centrosymmetric dimeric binuclear complex with two Cu2+ cations bridged by two oxygen atoms from two organic ligands. In the complexes, a very strong antiferromagnetic exchange interaction between copper atoms is observed.

AB - Two types of binuclear copper complexes [LCuN3]2 and [LCuNO3]2.of bidentate ligand - diphenyl-(1-propylbenzimidazol-2-yl)methanol (HL) in the 4:1 ratio were synthesized. The crystal structure of copper complexes shows a centrosymmetric dimeric binuclear complex with two Cu2+ cations bridged by two oxygen atoms from two organic ligands. In the complexes, a very strong antiferromagnetic exchange interaction between copper atoms is observed.

KW - antiferromagnetic exchange interaction

KW - benzimidazole

KW - binuclear copper complex

KW - X-ray diffraction

KW - CRYSTAL-STRUCTURE

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U2 - 10.1002/slct.201901186

DO - 10.1002/slct.201901186

M3 - Article

AN - SCOPUS:85070192055

VL - 4

SP - 8652

EP - 8654

JO - ChemistrySelect

JF - ChemistrySelect

SN - 2365-6549

IS - 29

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