Synthesis, Structure, and Luminescence Properties of a {Mo6I8} Complex with (C6F5)2PO2 Ligands

Alina D. Mironova; Maxim A. Mikhajlov; Taisiya S. Sukhikh; Konstantin A. Brylev; Artem L. Gushchin; Ilia V. Eltsov; Dmitri V. Stass; Evgeny I. Goryunov; Valery K. Brel; Maxim N. Sokolov

doi:10.1002/zaac.201900148

Synthesis, Structure, and Luminescence Properties of a {Mo₆I₈} Complex with (C₆F₅)₂PO₂ Ligands

Alina D. Mironova, Maxim A. Mikhajlov, Taisiya S. Sukhikh, Konstantin A. Brylev, Artem L. Gushchin, Ilia V. Eltsov, Dmitri V. Stass, Evgeny I. Goryunov, Valery K. Brel, Maxim N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

Reaction of [Mo₆I₈(CH₃COO)₆]^2– with bis(pentafluorophenyl)phosphinic acid HO(O)P(C₆F₅)₂ yielded a new bright-red luminescent complex [{Mo₆I₈}(O₂P(C₆F₅)₂)₆]^2–, isolated as (Bu₄N)(H₅O₂)[{Mo₆I₈}(O₂P(C₆F₅)₂)₆]·3(Et₂O)·1.5(acetone). It was characterized by X-ray analysis, CV, ESI-mass spectrometry, and NMR spectroscopy.

Язык оригинала	английский
Страницы (с-по)	1135-1140
Число страниц	6
Журнал	Zeitschrift fur Anorganische und Allgemeine Chemie
Том	645
Номер выпуска	18-19
DOI	https://doi.org/10.1002/zaac.201900148
Состояние	Опубликовано - 14 окт 2019

Доступ к документу

10.1002/zaac.201900148

Link to publication in Scopus

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Цитировать

Mironova, A. D., Mikhajlov, M. A., Sukhikh, T. S., Brylev, K. A., Gushchin, A. L., Eltsov, I. V., Stass, D. V., Goryunov, E. I., Brel, V. K., & Sokolov, M. N. (2019). Synthesis, Structure, and Luminescence Properties of a {Mo₆I₈} Complex with (C₆F₅)₂PO₂ Ligands. Zeitschrift fur Anorganische und Allgemeine Chemie, 645(18-19), 1135-1140. https://doi.org/10.1002/zaac.201900148

Mironova, Alina D. ; Mikhajlov, Maxim A. ; Sukhikh, Taisiya S. ; Brylev, Konstantin A. ; Gushchin, Artem L. ; Eltsov, Ilia V. ; Stass, Dmitri V. ; Goryunov, Evgeny I. ; Brel, Valery K. ; Sokolov, Maxim N. / Synthesis, Structure, and Luminescence Properties of a {Mo₆I₈} Complex with (C₆F₅)₂PO₂ Ligands. В: Zeitschrift fur Anorganische und Allgemeine Chemie. 2019 ; Том 645, № 18-19. стр. 1135-1140.

@article{821833b7036a447780d1de9a052db5ea,

title = "Synthesis, Structure, and Luminescence Properties of a {Mo6I8} Complex with (C6F5)2PO2 Ligands",

abstract = "Reaction of [Mo6I8(CH3COO)6]2– with bis(pentafluorophenyl)phosphinic acid HO(O)P(C6F5)2 yielded a new bright-red luminescent complex [{Mo6I8}(O2P(C6F5)2)6]2–, isolated as (Bu4N)(H5O2)[{Mo6I8}(O2P(C6F5)2)6]·3(Et2O)·1.5(acetone). It was characterized by X-ray analysis, CV, ESI-mass spectrometry, and NMR spectroscopy.",

keywords = "Electrochemistry, Luminescence, Molybdenum iodide cluster, Perfluorinated ligands, Phosphinic acids, BR, IODIDE CLUSTER, MOLYBDENUM CLUSTER COMPLEXES, SILICA NANOPARTICLES, REDOX, CL",

author = "Mironova, {Alina D.} and Mikhajlov, {Maxim A.} and Sukhikh, {Taisiya S.} and Brylev, {Konstantin A.} and Gushchin, {Artem L.} and Eltsov, {Ilia V.} and Stass, {Dmitri V.} and Goryunov, {Evgeny I.} and Brel, {Valery K.} and Sokolov, {Maxim N.}",

year = "2019",

month = oct,

day = "14",

doi = "10.1002/zaac.201900148",

language = "English",

volume = "645",

pages = "1135--1140",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "18-19",

}

Synthesis, Structure, and Luminescence Properties of a {Mo₆I₈} Complex with (C₆F₅)₂PO₂ Ligands. / Mironova, Alina D.; Mikhajlov, Maxim A.; Sukhikh, Taisiya S.; Brylev, Konstantin A.; Gushchin, Artem L.; Eltsov, Ilia V.; Stass, Dmitri V.; Goryunov, Evgeny I.; Brel, Valery K.; Sokolov, Maxim N.

В: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 645, № 18-19, 14.10.2019, стр. 1135-1140.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Synthesis, Structure, and Luminescence Properties of a {Mo6I8} Complex with (C6F5)2PO2 Ligands

AU - Mironova, Alina D.

AU - Mikhajlov, Maxim A.

AU - Sukhikh, Taisiya S.

AU - Brylev, Konstantin A.

AU - Gushchin, Artem L.

AU - Eltsov, Ilia V.

AU - Stass, Dmitri V.

AU - Goryunov, Evgeny I.

AU - Brel, Valery K.

AU - Sokolov, Maxim N.

PY - 2019/10/14

Y1 - 2019/10/14

N2 - Reaction of [Mo6I8(CH3COO)6]2– with bis(pentafluorophenyl)phosphinic acid HO(O)P(C6F5)2 yielded a new bright-red luminescent complex [{Mo6I8}(O2P(C6F5)2)6]2–, isolated as (Bu4N)(H5O2)[{Mo6I8}(O2P(C6F5)2)6]·3(Et2O)·1.5(acetone). It was characterized by X-ray analysis, CV, ESI-mass spectrometry, and NMR spectroscopy.

AB - Reaction of [Mo6I8(CH3COO)6]2– with bis(pentafluorophenyl)phosphinic acid HO(O)P(C6F5)2 yielded a new bright-red luminescent complex [{Mo6I8}(O2P(C6F5)2)6]2–, isolated as (Bu4N)(H5O2)[{Mo6I8}(O2P(C6F5)2)6]·3(Et2O)·1.5(acetone). It was characterized by X-ray analysis, CV, ESI-mass spectrometry, and NMR spectroscopy.

KW - Electrochemistry

KW - Luminescence

KW - Molybdenum iodide cluster

KW - Perfluorinated ligands

KW - Phosphinic acids

KW - BR

KW - IODIDE CLUSTER

KW - MOLYBDENUM CLUSTER COMPLEXES

KW - SILICA NANOPARTICLES

KW - REDOX

KW - CL

UR - http://www.scopus.com/inward/record.url?scp=85073554762&partnerID=8YFLogxK

U2 - 10.1002/zaac.201900148

DO - 10.1002/zaac.201900148

M3 - Article

AN - SCOPUS:85073554762

VL - 645

SP - 1135

EP - 1140

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 18-19

ER -