Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid

D. N. Sokolov; O. A. Luzina; N. F. Salakhutdinov

doi:10.1007/s10600-018-2256-8

Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid

D. N. Sokolov, O. A. Luzina, N. F. Salakhutdinov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

Sulfones were produced by meta-chloroperbenzoic-acid oxidation of the corresponding thioethers prepared from (+)-usnic acid. Reaction of the thioethers with H₂O₂ in the presence of VO(acac)₂ formed a mixture of sulfoxide diastereomers. Possible chiral oxidation of the thioethers into sulfoxides was studied.

Язык оригинала	английский
Страницы (с-по)	46-49
Число страниц	4
Журнал	Chemistry of Natural Compounds
Том	54
Номер выпуска	1
DOI	https://doi.org/10.1007/s10600-018-2256-8
Состояние	Опубликовано - 1 янв 2018

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10.1007/s10600-018-2256-8

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abstract = "Sulfones were produced by meta-chloroperbenzoic-acid oxidation of the corresponding thioethers prepared from (+)-usnic acid. Reaction of the thioethers with H2O2 in the presence of VO(acac)2 formed a mixture of sulfoxide diastereomers. Possible chiral oxidation of the thioethers into sulfoxides was studied.",

keywords = "(+)-usnic acid, chiral oxidation, sulfones, sulfoxidation, thioethers",

author = "Sokolov, {D. N.} and Luzina, {O. A.} and Salakhutdinov, {N. F.}",

year = "2018",

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doi = "10.1007/s10600-018-2256-8",

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Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid. / Sokolov, D. N.; Luzina, O. A.; Salakhutdinov, N. F.

В: Chemistry of Natural Compounds, Том 54, № 1, 01.01.2018, стр. 46-49.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid

AU - Sokolov, D. N.

AU - Luzina, O. A.

AU - Salakhutdinov, N. F.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Sulfones were produced by meta-chloroperbenzoic-acid oxidation of the corresponding thioethers prepared from (+)-usnic acid. Reaction of the thioethers with H2O2 in the presence of VO(acac)2 formed a mixture of sulfoxide diastereomers. Possible chiral oxidation of the thioethers into sulfoxides was studied.

AB - Sulfones were produced by meta-chloroperbenzoic-acid oxidation of the corresponding thioethers prepared from (+)-usnic acid. Reaction of the thioethers with H2O2 in the presence of VO(acac)2 formed a mixture of sulfoxide diastereomers. Possible chiral oxidation of the thioethers into sulfoxides was studied.

KW - (+)-usnic acid

KW - chiral oxidation

KW - sulfones

KW - sulfoxidation

KW - thioethers

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U2 - 10.1007/s10600-018-2256-8

DO - 10.1007/s10600-018-2256-8

M3 - Article

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VL - 54

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EP - 49

JO - Chemistry of Natural Compounds

JF - Chemistry of Natural Compounds

SN - 0009-3130

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Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid

Аннотация

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