Synthesis of 1-(Adamantan-1-yl)-1H-1,2,3-Triazoles and their Salts by Adamantylation in AdOH–HClO4 and AdOH–H2SO4 Systems

Gennady T. Sukhanov, Yuliya V. Filippova, Anna G. Sukhanova, Irina Yu Bagryanskaya, Konstantin K. Bosov

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

[Figure not available: see fulltext.] 1-(Adamantan-1-yl)-1H-1,2,3-triazoles and a series of 1-(adamantan-1-yl)-3-alkyl-1,2,3-triazolium salts were synthesized by regioselective adamantylation of 1,2,3-triazole derivatives. The direction of the attack by the adamantyl cation at the N-1 nitrogen atom and the regioselectivity of the processes of adamantylation and quaternization are ensured by a number of factors: the specificity of the properties of the high-acid systems AdOH–HClO4 and AdOH–H2SO4, as well as the structural aspect and high reactivity of adamantan-1-ol.

Язык оригиналаанглийский
Страницы (с-по)1197-1203
Число страниц7
ЖурналChemistry of Heterocyclic Compounds
Том55
Номер выпуска12
DOI
СостояниеОпубликовано - 1 дек 2019

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