Аннотация
[Figure not available: see fulltext.] 1-(Adamantan-1-yl)-1H-1,2,3-triazoles and a series of 1-(adamantan-1-yl)-3-alkyl-1,2,3-triazolium salts were synthesized by regioselective adamantylation of 1,2,3-triazole derivatives. The direction of the attack by the adamantyl cation at the N-1 nitrogen atom and the regioselectivity of the processes of adamantylation and quaternization are ensured by a number of factors: the specificity of the properties of the high-acid systems AdOH–HClO4 and AdOH–H2SO4, as well as the structural aspect and high reactivity of adamantan-1-ol.
Язык оригинала | английский |
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Страницы (с-по) | 1197-1203 |
Число страниц | 7 |
Журнал | Chemistry of Heterocyclic Compounds |
Том | 55 |
Номер выпуска | 12 |
DOI | |
Состояние | Опубликовано - 1 дек 2019 |