Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

Pavel A. Petrov; Dmitry Yu Naumov; Taisiya S. Sukhikh; Sergey N. Konchenko; Carlos J. Gómez-García; Rosa Llusar

doi:10.1039/c7nj01217a

Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo₃S₄Ga cores

Pavel A. Petrov, Dmitry Yu Naumov, Taisiya S. Sukhikh, Sergey N. Konchenko, Carlos J. Gómez-García, Rosa Llusar

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

Electron precise [Mo₃(μ₃-S)(μ-S)₃(diphos)₃Br₃]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo₃(GaBr)(μ₃-S)₄(diphos)₃Br₃] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.

Язык оригинала	английский
Страницы (с-по)	7849-7852
Число страниц	4
Журнал	New Journal of Chemistry
Том	41
Номер выпуска	16
DOI	https://doi.org/10.1039/c7nj01217a
Состояние	Опубликовано - 21 авг. 2017

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10.1039/c7nj01217a

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title = "Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores",

abstract = "Electron precise [Mo3(μ3-S)(μ-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(μ3-S)4(diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.",

keywords = "X-RAY-STRUCTURE, MIXED-METAL CLUSTER, SHARED DOUBLE CUBE, MOLYBDENUM, COMPLEXES, DERIVATIVES, REACTIVITY, SINGLE, MO",

author = "Petrov, {Pavel A.} and Naumov, {Dmitry Yu} and Sukhikh, {Taisiya S.} and Konchenko, {Sergey N.} and G{\'o}mez-Garc{\'i}a, {Carlos J.} and Rosa Llusar",

year = "2017",

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doi = "10.1039/c7nj01217a",

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Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo₃S₄Ga cores. / Petrov, Pavel A.; Naumov, Dmitry Yu; Sukhikh, Taisiya S. и др.

В: New Journal of Chemistry, Том 41, № 16, 21.08.2017, стр. 7849-7852.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

AU - Petrov, Pavel A.

AU - Naumov, Dmitry Yu

AU - Sukhikh, Taisiya S.

AU - Konchenko, Sergey N.

AU - Gómez-García, Carlos J.

AU - Llusar, Rosa

PY - 2017/8/21

Y1 - 2017/8/21

N2 - Electron precise [Mo3(μ3-S)(μ-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(μ3-S)4(diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.

AB - Electron precise [Mo3(μ3-S)(μ-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(μ3-S)4(diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.

KW - X-RAY-STRUCTURE

KW - MIXED-METAL CLUSTER

KW - SHARED DOUBLE CUBE

KW - MOLYBDENUM

KW - COMPLEXES

KW - DERIVATIVES

KW - REACTIVITY

KW - SINGLE

KW - MO

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DO - 10.1039/c7nj01217a

M3 - Article

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VL - 41

SP - 7849

EP - 7852

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

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