Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer

T. K. Koltunova; D. G. Samsonenko; M. I. Rakhmanova; D. N. Dybtsev; V. P. Fedin

doi:10.1007/s11172-015-1245-3

Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer

T. K. Koltunova, D. G. Samsonenko, M. I. Rakhmanova, D. N. Dybtsev, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья

2 Цитирования (Scopus)

Аннотация

A metal-organic coordination polymer of the formula [Li₃(btc)(H₂O)] (1a) (H₃btc is the trimesic acid, C₆H₃(COOH)₃) was obtained upon heating a mixture of LiBH₄ and H₃btc in ethanol. The structure was established by single crystal X-ray diffraction study. The studies by TGA show that polymer 1a loses the coordinated water at T ≥ 250 °C, whereas the metal-organic framework of lithium trimesate disintegrates only above 500 °C. The luminescence spectra showed a considerable (5-fold) increase in luminescence intensity and a bathochromic shift upon dehydration of 1a.

Язык оригинала	английский
Страницы (с-по)	2903-2907
Число страниц	5
Журнал	Russian Chemical Bulletin
Том	64
Номер выпуска	12
DOI	https://doi.org/10.1007/s11172-015-1245-3
Состояние	Опубликовано - 1 дек 2015

Доступ к документу

10.1007/s11172-015-1245-3

Link to publication in Scopus

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title = "Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer",

abstract = "A metal-organic coordination polymer of the formula [Li3(btc)(H2O)] (1a) (H3btc is the trimesic acid, C6H3(COOH)3) was obtained upon heating a mixture of LiBH4 and H3btc in ethanol. The structure was established by single crystal X-ray diffraction study. The studies by TGA show that polymer 1a loses the coordinated water at T ≥ 250 °C, whereas the metal-organic framework of lithium trimesate disintegrates only above 500 °C. The luminescence spectra showed a considerable (5-fold) increase in luminescence intensity and a bathochromic shift upon dehydration of 1a.",

keywords = "cage structures, coordination polymers, lithium(I) complexes, luminescence, X-ray crystallography",

author = "Koltunova, {T. K.} and Samsonenko, {D. G.} and Rakhmanova, {M. I.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

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Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer. / Koltunova, T. K.; Samsonenko, D. G.; Rakhmanova, M. I.; Dybtsev, D. N.; Fedin, V. P.

В: Russian Chemical Bulletin, Том 64, № 12, 01.12.2015, стр. 2903-2907.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer

AU - Koltunova, T. K.

AU - Samsonenko, D. G.

AU - Rakhmanova, M. I.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2015/12/1

Y1 - 2015/12/1

N2 - A metal-organic coordination polymer of the formula [Li3(btc)(H2O)] (1a) (H3btc is the trimesic acid, C6H3(COOH)3) was obtained upon heating a mixture of LiBH4 and H3btc in ethanol. The structure was established by single crystal X-ray diffraction study. The studies by TGA show that polymer 1a loses the coordinated water at T ≥ 250 °C, whereas the metal-organic framework of lithium trimesate disintegrates only above 500 °C. The luminescence spectra showed a considerable (5-fold) increase in luminescence intensity and a bathochromic shift upon dehydration of 1a.

AB - A metal-organic coordination polymer of the formula [Li3(btc)(H2O)] (1a) (H3btc is the trimesic acid, C6H3(COOH)3) was obtained upon heating a mixture of LiBH4 and H3btc in ethanol. The structure was established by single crystal X-ray diffraction study. The studies by TGA show that polymer 1a loses the coordinated water at T ≥ 250 °C, whereas the metal-organic framework of lithium trimesate disintegrates only above 500 °C. The luminescence spectra showed a considerable (5-fold) increase in luminescence intensity and a bathochromic shift upon dehydration of 1a.

KW - cage structures

KW - coordination polymers

KW - lithium(I) complexes

KW - luminescence

KW - X-ray crystallography

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U2 - 10.1007/s11172-015-1245-3

DO - 10.1007/s11172-015-1245-3

M3 - Article

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VL - 64

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EP - 2907

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 12

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