Synthesis and Study of Bimetallic Pd-Rh System Supported on Zirconia-Doped Alumina as a Component of Three-way Catalysts

Aleksey A. Vedyagin, Roman M. Kenzhin, Mikhail Yu Tashlanov, Vladimir O. Stoyanovskii, Pavel E. Plyusnin, Yury V. Shubin, Ilya V. Mishakov, Alexander V. Kalinkin, Mikhail Yu Smirnov, Valerii I. Bukhtiyarov

Результат исследования: Научные публикации в периодических изданияхстатьярецензирование

3 Цитирования (Scopus)


The present work is aimed at preparation and detailed characterization of the Pd-Rh/γ-Al2O3-ZrO2 composition used as a component of three-way catalysts. Physicochemical properties, such as specific surface area, morphology, secondary structure, dispersity and chemical state of active components, and thermal stability along with catalytic activity were studied within this research. Textural parameters of the samples were examined using low-temperature nitrogen adsorption. Analysis of the morphology and secondary structure was performed by means of electron microscopy. Concentration of metals located on the surface and accessible for the reagents was estimated using test reaction of ethane hydrogenolysis. Method of X-ray photoelectron spectroscopy was applied to investigate the chemical state of active components. Catalytic performance and thermal stability of the samples were tested in a prompt thermal aging regime using CO oxidation reaction as a criterion for in situ characterization of the catalyst state. It was found that both these characteristics strongly depend on the nature and composition of the precursors used.

Язык оригиналаанглийский
Страницы (с-по)363-377
Число страниц15
ЖурналEmission Control Science and Technology
Номер выпуска4
СостояниеОпубликовано - 15 дек 2019

Предметные области OECD FOS+WOS



Подробные сведения о темах исследования «Synthesis and Study of Bimetallic Pd-Rh System Supported on Zirconia-Doped Alumina as a Component of Three-way Catalysts». Вместе они формируют уникальный семантический отпечаток (fingerprint).