Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien*)PtCl                         
                        3
                                                 ] and [AuCl(μ-Dien*)PtCl                         
                        3
                                                 ] · 0.5H                         
                        2
                                                 O

E. V. Makotchenko; I. A. Baidina; I. V. Korol’kov

doi:10.1134/S0036023619010157

Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien)PtCl ₃ ] and [AuCl(μ-Dien)PtCl ₃ ] · 0.5H ₂ O

E. V. Makotchenko, I. A. Baidina, I. V. Korol’kov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

New binuclear complexes [AuCl(μ-Dien*)PtCl ₃ ] and [AuCl(μ-Dien*)PtCl ₃ ] · 0.5H ₂ O, where Dien* is deprotonated diethylenetriamine, have been prepared and studied by elemental analysis, X-ray diffraction, and IR spectroscopy. The crystal structures are built of binuclear complexes of the composition [AuCl(μ-Dien*)PtCl ₃ ] with the average Au⋯Pt intramolecular distance equal to 3.403 Å. Gold and platinum atoms have distorted square coordination; the (AuN ₃ Cl) and (PtNCl ₃ ) coordination cores are found; the middle Dien nitrogen atom acts as a bridge bonding the Au and Pt coordination squares.

Язык оригинала	английский
Страницы (с-по)	41-48
Число страниц	8
Журнал	Russian Journal of Inorganic Chemistry
Том	64
Номер выпуска	1
DOI	https://doi.org/10.1134/S0036023619010157
Состояние	Опубликовано - 1 янв 2019

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10.1134/S0036023619010157

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Makotchenko, E. V., Baidina, I. A., & Korol’kov, I. V. (2019). Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien*)PtCl ₃ ] and [AuCl(μ-Dien*)PtCl ₃ ] · 0.5H ₂ O. Russian Journal of Inorganic Chemistry, 64(1), 41-48. https://doi.org/10.1134/S0036023619010157

Makotchenko, E. V. ; Baidina, I. A. ; Korol’kov, I. V. / Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien*)PtCl ₃ ] and [AuCl(μ-Dien*)PtCl ₃ ] · 0.5H ₂ O. В: Russian Journal of Inorganic Chemistry. 2019 ; Том 64, № 1. стр. 41-48.

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title = "Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien*)PtCl 3 ] and [AuCl(μ-Dien*)PtCl 3 ] · 0.5H 2 O",

abstract = " New binuclear complexes [AuCl(μ-Dien*)PtCl 3 ] and [AuCl(μ-Dien*)PtCl 3 ] · 0.5H 2 O, where Dien* is deprotonated diethylenetriamine, have been prepared and studied by elemental analysis, X-ray diffraction, and IR spectroscopy. The crystal structures are built of binuclear complexes of the composition [AuCl(μ-Dien*)PtCl 3 ] with the average Au⋯Pt intramolecular distance equal to 3.403 {\AA}. Gold and platinum atoms have distorted square coordination; the (AuN 3 Cl) and (PtNCl 3 ) coordination cores are found; the middle Dien nitrogen atom acts as a bridge bonding the Au and Pt coordination squares. ",

keywords = "diethylenetriamine, gold, platinum, X-ray diffraction, CRYSTAL-STRUCTURE, SALTS",

author = "Makotchenko, {E. V.} and Baidina, {I. A.} and Korol{\textquoteright}kov, {I. V.}",

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Makotchenko, EV, Baidina, IA & Korol’kov, IV 2019, 'Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien*)PtCl ₃ ] and [AuCl(μ-Dien*)PtCl ₃ ] · 0.5H ₂ O', Russian Journal of Inorganic Chemistry, том. 64, № 1, стр. 41-48. https://doi.org/10.1134/S0036023619010157

Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien*)PtCl ₃ ] and [AuCl(μ-Dien*)PtCl ₃ ] · 0.5H ₂ O. / Makotchenko, E. V.; Baidina, I. A.; Korol’kov, I. V.

В: Russian Journal of Inorganic Chemistry, Том 64, № 1, 01.01.2019, стр. 41-48.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien*)PtCl 3 ] and [AuCl(μ-Dien*)PtCl 3 ] · 0.5H 2 O

AU - Makotchenko, E. V.

AU - Baidina, I. A.

AU - Korol’kov, I. V.

PY - 2019/1/1

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AB - New binuclear complexes [AuCl(μ-Dien*)PtCl 3 ] and [AuCl(μ-Dien*)PtCl 3 ] · 0.5H 2 O, where Dien* is deprotonated diethylenetriamine, have been prepared and studied by elemental analysis, X-ray diffraction, and IR spectroscopy. The crystal structures are built of binuclear complexes of the composition [AuCl(μ-Dien*)PtCl 3 ] with the average Au⋯Pt intramolecular distance equal to 3.403 Å. Gold and platinum atoms have distorted square coordination; the (AuN 3 Cl) and (PtNCl 3 ) coordination cores are found; the middle Dien nitrogen atom acts as a bridge bonding the Au and Pt coordination squares.

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Makotchenko EV, Baidina IA, Korol’kov IV. Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien*)PtCl ₃ ] and [AuCl(μ-Dien*)PtCl ₃ ] · 0.5H ₂ O. Russian Journal of Inorganic Chemistry. 2019 Янв. 1;64(1):41-48. https://doi.org/10.1134/S0036023619010157