Аннотация
New binuclear complexes [AuCl(μ-Dien*)PtCl 3 ] and [AuCl(μ-Dien*)PtCl 3 ] · 0.5H 2 O, where Dien* is deprotonated diethylenetriamine, have been prepared and studied by elemental analysis, X-ray diffraction, and IR spectroscopy. The crystal structures are built of binuclear complexes of the composition [AuCl(μ-Dien*)PtCl 3 ] with the average Au⋯Pt intramolecular distance equal to 3.403 Å. Gold and platinum atoms have distorted square coordination; the (AuN 3 Cl) and (PtNCl 3 ) coordination cores are found; the middle Dien nitrogen atom acts as a bridge bonding the Au and Pt coordination squares.
Язык оригинала | английский |
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Страницы (с-по) | 41-48 |
Число страниц | 8 |
Журнал | Russian Journal of Inorganic Chemistry |
Том | 64 |
Номер выпуска | 1 |
DOI | |
Состояние | Опубликовано - 1 янв 2019 |