@article{09b03b30777d4bed97a5f8fee3a8c48f,
title = "Synthesis and Structure of [Fe3(μ3-Q)(μ3-AsN(i-Bu)2)(CO)9] (Q = Se, Te) Clusters and Products of Their Hydrolysis",
abstract = "New iron clusters [Fe3(μ3-Q)(μ3-AsN(i-Bu)2)(CO)9] (Q = Se (1a) and Te (1b)) are synthesized. Hydrolysis reactions of these compounds that break the As-N bond are studied. The structures of clusters 1a,b and products of hydrolysis, namely [Fe6(μ6,η2-AsOAs)(μ3-Te)2(CO)18] (2), [NH2(i-Bu)2][Fe3(μ3-Se)×× (μ3-AsO)(CO)9] (3), and [{Fe3(μ3-Se)(μ4-As)(CO)9}2{Fe2(μ2-Se)2 (CO)5}] (4) are determined by the single crystal X-ray diffraction analysis.",
keywords = "arsenic, carbonyl cluster, chalcogen, crystal structure, iron, synthesis, ELECTROCHEMICAL PROPERTIES, MOLECULAR-STRUCTURE, COMPLEXES, (MU-H)(2)FE-3(MU(3)-SE)(CO)(9), IRON, CRYSTAL, MODELS, PROTON REDUCTION, METAL SUBSTITUTION-REACTION, TELLURIDE",
author = "Bashirov, {D. A.} and Sukhikh, {T. S.} and Kuratieva, {N. V.} and Konchenko, {S. N.}",
year = "2020",
month = feb,
day = "1",
doi = "10.1134/S0022476620020134",
language = "English",
volume = "61",
pages = "283--292",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",
}