Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH3)3(NO2)(H2O)](NO3)2

Vasily Vorobyev; Evgeniy V. Kabin; Vyacheslav A. Emelyanov; Iraida A. Baidina; Ilya V. Korolkov

doi:10.1016/j.inoche.2016.03.019

Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH₃)₃(NO₂)(H₂O)](NO₃)₂

Vasily Vorobyev, Evgeniy V. Kabin, Vyacheslav A. Emelyanov, Iraida A. Baidina, Ilya V. Korolkov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

13 Цитирования (Scopus)

Аннотация

The reaction between mer-[RuNO(NH₃)₃(NO₂)(OH)]Cl·0.5H₂O and an excess of 16 M HNO₃ leads to the protonation of the starting complex and crystallization of the complex with a coordinated water molecule and nitrite anion. The crystal structure of the product has been determined. The coordinated water molecule tends to be a weak acid with a measured pK_a of 2.4.

Язык оригинала	английский
Страницы (с-по)	1-3
Число страниц	3
Журнал	Inorganic Chemistry Communications
Том	68
DOI	https://doi.org/10.1016/j.inoche.2016.03.019
Состояние	Опубликовано - июн 2016

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10.1016/j.inoche.2016.03.019

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title = "Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH3)3(NO2)(H2O)](NO3)2",

abstract = "The reaction between mer-[RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O and an excess of 16 M HNO3 leads to the protonation of the starting complex and crystallization of the complex with a coordinated water molecule and nitrite anion. The crystal structure of the product has been determined. The coordinated water molecule tends to be a weak acid with a measured pKa of 2.4.",

keywords = "Aqua complex, Metastable states, Nitro complex, Nitrosyl, Photoactivity, Ruthenium",

author = "Vasily Vorobyev and Kabin, {Evgeniy V.} and Emelyanov, {Vyacheslav A.} and Baidina, {Iraida A.} and Korolkov, {Ilya V.}",

year = "2016",

month = jun,

doi = "10.1016/j.inoche.2016.03.019",

language = "English",

volume = "68",

pages = "1--3",

journal = "Inorganic Chemistry Communication",

issn = "1387-7003",

publisher = "Elsevier",

}

Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH₃)₃(NO₂)(H₂O)](NO₃)₂. / Vorobyev, Vasily; Kabin, Evgeniy V.; Emelyanov, Vyacheslav A.; Baidina, Iraida A.; Korolkov, Ilya V.

В: Inorganic Chemistry Communications, Том 68, 06.2016, стр. 1-3.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH3)3(NO2)(H2O)](NO3)2

AU - Vorobyev, Vasily

AU - Kabin, Evgeniy V.

AU - Emelyanov, Vyacheslav A.

AU - Baidina, Iraida A.

AU - Korolkov, Ilya V.

PY - 2016/6

Y1 - 2016/6

N2 - The reaction between mer-[RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O and an excess of 16 M HNO3 leads to the protonation of the starting complex and crystallization of the complex with a coordinated water molecule and nitrite anion. The crystal structure of the product has been determined. The coordinated water molecule tends to be a weak acid with a measured pKa of 2.4.

AB - The reaction between mer-[RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O and an excess of 16 M HNO3 leads to the protonation of the starting complex and crystallization of the complex with a coordinated water molecule and nitrite anion. The crystal structure of the product has been determined. The coordinated water molecule tends to be a weak acid with a measured pKa of 2.4.

KW - Aqua complex

KW - Metastable states

KW - Nitro complex

KW - Nitrosyl

KW - Photoactivity

KW - Ruthenium

UR - http://www.scopus.com/inward/record.url?scp=84962848889&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2016.03.019

DO - 10.1016/j.inoche.2016.03.019

M3 - Article

AN - SCOPUS:84962848889

VL - 68

SP - 1

EP - 3

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -