Synthesis and Crystal Structure of Dinitratotetra(hexamethylphosphoric Triamide)-Lanthanum(III)Tetra(Isothiocyanato)Diammine Chromate(III)

A. A. Bobrovnikova; E. V. Peresypkina; A. V. Virovets; T. G. Cherkasova; E. S. Tatarinova

doi:10.1134/S0036023618010047

Synthesis and Crystal Structure of Dinitratotetra(hexamethylphosphoric Triamide)-Lanthanum(III)Tetra(Isothiocyanato)Diammine Chromate(III)

A. A. Bobrovnikova, E. V. Peresypkina, A. V. Virovets, T. G. Cherkasova, E. S. Tatarinova

Лаборатория методов исследования состава и структуры функциональных материалов ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

A new coordination compound having the formula [La(HMPA)₄(NO₃)₂][Cr(NH₃)₂(NCS)₄] (I), where HMPA is ((CH₃)₂N)₃PO, has been synthesized and studied by X-ray diffraction. Studied crystals of compound I are monoclinic, space group P2₁/n, a = 15.0360(3) Å, b = 15.1214(3) Å, c = 26.7529(7) Å, β = 100.6610(10)°, V = 5977.7(9) Å3, Z = 2, ρ_calc = 1.442 g/cm³, and R₁ = 0.0453 for 7344 reflections with F_o ≥ 4σ(F_o).

Язык оригинала	английский
Страницы (с-по)	34-39
Число страниц	6
Журнал	Russian Journal of Inorganic Chemistry
Том	63
Номер выпуска	1
DOI	https://doi.org/10.1134/S0036023618010047
Состояние	Опубликовано - 1 янв 2018

Доступ к документу

10.1134/S0036023618010047

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@article{a48f14b3ed944175a3eb503cffc2d5f7,

title = "Synthesis and Crystal Structure of Dinitratotetra(hexamethylphosphoric Triamide)-Lanthanum(III)Tetra(Isothiocyanato)Diammine Chromate(III)",

abstract = "A new coordination compound having the formula [La(HMPA)4(NO3)2][Cr(NH3)2(NCS)4] (I), where HMPA is ((CH3)2N)3PO, has been synthesized and studied by X-ray diffraction. Studied crystals of compound I are monoclinic, space group P21/n, a = 15.0360(3) {\AA}, b = 15.1214(3) {\AA}, c = 26.7529(7) {\AA}, β = 100.6610(10)°, V = 5977.7(9) {\AA}3, Z = 2, ρcalc = 1.442 g/cm3, and R1 = 0.0453 for 7344 reflections with Fo ≥ 4σ(Fo).",

keywords = "HEXAMETHYLPHOSPHORAMIDE-COORDINATED COMPLEXES, HMPA, LA, EU, SM, LN",

author = "Bobrovnikova, {A. A.} and Peresypkina, {E. V.} and Virovets, {A. V.} and Cherkasova, {T. G.} and Tatarinova, {E. S.}",

year = "2018",

month = jan,

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doi = "10.1134/S0036023618010047",

language = "English",

volume = "63",

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journal = "Russian Journal of Inorganic Chemistry",

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Synthesis and Crystal Structure of Dinitratotetra(hexamethylphosphoric Triamide)-Lanthanum(III)Tetra(Isothiocyanato)Diammine Chromate(III). / Bobrovnikova, A. A.; Peresypkina, E. V.; Virovets, A. V.; Cherkasova, T. G.; Tatarinova, E. S.

В: Russian Journal of Inorganic Chemistry, Том 63, № 1, 01.01.2018, стр. 34-39.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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T1 - Synthesis and Crystal Structure of Dinitratotetra(hexamethylphosphoric Triamide)-Lanthanum(III)Tetra(Isothiocyanato)Diammine Chromate(III)

AU - Bobrovnikova, A. A.

AU - Peresypkina, E. V.

AU - Virovets, A. V.

AU - Cherkasova, T. G.

AU - Tatarinova, E. S.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - A new coordination compound having the formula [La(HMPA)4(NO3)2][Cr(NH3)2(NCS)4] (I), where HMPA is ((CH3)2N)3PO, has been synthesized and studied by X-ray diffraction. Studied crystals of compound I are monoclinic, space group P21/n, a = 15.0360(3) Å, b = 15.1214(3) Å, c = 26.7529(7) Å, β = 100.6610(10)°, V = 5977.7(9) Å3, Z = 2, ρcalc = 1.442 g/cm3, and R1 = 0.0453 for 7344 reflections with Fo ≥ 4σ(Fo).

AB - A new coordination compound having the formula [La(HMPA)4(NO3)2][Cr(NH3)2(NCS)4] (I), where HMPA is ((CH3)2N)3PO, has been synthesized and studied by X-ray diffraction. Studied crystals of compound I are monoclinic, space group P21/n, a = 15.0360(3) Å, b = 15.1214(3) Å, c = 26.7529(7) Å, β = 100.6610(10)°, V = 5977.7(9) Å3, Z = 2, ρcalc = 1.442 g/cm3, and R1 = 0.0453 for 7344 reflections with Fo ≥ 4σ(Fo).

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KW - HMPA

KW - LA

KW - EU

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KW - LN

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