Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives

M. S. Zavakhina; D. G. Samsonenko; D. N. Dybtsev; S. P. Argent; A. J. Blake; M. Schröder; V. P. Fedin

doi:10.1007/s11172-015-1246-2

Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives

M. S. Zavakhina, D. G. Samsonenko, D. N. Dybtsev, S. P. Argent, A. J. Blake, M. Schröder, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

2 Цитирования (Scopus)

Аннотация

Chiral 2D and 3D metal-organic coordination polymers [Cu₂(bpy)₂(Hdml)₂(HCOO)]-(HCOO)·2H₂O (1) and [Cu(bpy)(Hphl)(HCOO)]·H₂O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H₂dml) or S-3-phenyllactic (H₂phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

Язык оригинала	английский
Страницы (с-по)	2908-2913
Число страниц	6
Журнал	Russian Chemical Bulletin
Том	64
Номер выпуска	12
DOI	https://doi.org/10.1007/s11172-015-1246-2
Состояние	Опубликовано - 1 дек. 2015

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10.1007/s11172-015-1246-2

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title = "Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives",

abstract = "Chiral 2D and 3D metal-organic coordination polymers [Cu2(bpy)2(Hdml)2(HCOO)]-(HCOO)·2H2O (1) and [Cu(bpy)(Hphl)(HCOO)]·H2O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H2dml) or S-3-phenyllactic (H2phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.",

keywords = "chiral complexes, coordination polymers, copper, crystal structure, supramolecular interactions",

author = "Zavakhina, {M. S.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Argent, {S. P.} and Blake, {A. J.} and M. Schr{\"o}der and Fedin, {V. P.}",

year = "2015",

month = dec,

day = "1",

doi = "10.1007/s11172-015-1246-2",

language = "English",

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journal = "Russian Chemical Bulletin",

issn = "1066-5285",

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number = "12",

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Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives. / Zavakhina, M. S.; Samsonenko, D. G.; Dybtsev, D. N. и др.

В: Russian Chemical Bulletin, Том 64, № 12, 01.12.2015, стр. 2908-2913.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Synthesis and characterization of chiral copper(ii) coordination polymers with 4,4´-bipyridine and lactic acid derivatives

AU - Zavakhina, M. S.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Argent, S. P.

AU - Blake, A. J.

AU - Schröder, M.

AU - Fedin, V. P.

PY - 2015/12/1

Y1 - 2015/12/1

N2 - Chiral 2D and 3D metal-organic coordination polymers [Cu2(bpy)2(Hdml)2(HCOO)]-(HCOO)·2H2O (1) and [Cu(bpy)(Hphl)(HCOO)]·H2O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H2dml) or S-3-phenyllactic (H2phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

AB - Chiral 2D and 3D metal-organic coordination polymers [Cu2(bpy)2(Hdml)2(HCOO)]-(HCOO)·2H2O (1) and [Cu(bpy)(Hphl)(HCOO)]·H2O (2) were synthesized by heating a solution of copper(ii) salts, 4,4´-bipyridine (bpy), and α-hydroxycarboxylic acids, viz., S-3,3-dimethyllactic (H2dml) or S-3-phenyllactic (H2phl) acid, in a water—N,N´-dimethylformamide mixture. The structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction. Compound 2 was characterized by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

KW - chiral complexes

KW - coordination polymers

KW - copper

KW - crystal structure

KW - supramolecular interactions

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U2 - 10.1007/s11172-015-1246-2

DO - 10.1007/s11172-015-1246-2

M3 - Article

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VL - 64

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JO - Russian Chemical Bulletin

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