Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands

D. S. Ogienko; A. I. Smolentsev; D. A. Bashirov; M. Yu Afonin; P. A. Petrov; S. N. Konchenko

doi:10.1134/S1070328415110056

Syntheses and structures of complexes {Mo₂S₂O₂}²⁺ with labile Cl^- and DMF ligands

D. S. Ogienko, A. I. Smolentsev, D. A. Bashirov, M. Yu Afonin, P. A. Petrov, S. N. Konchenko

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

Complex (Me₄N)₂[Mo₂S₂O₂Cl₄] ((Me₄N)₂[II]) is synthesized by passing gaseous HCl through a solution of (Me₄N)₂[Mo₂O₂S₈] ((Me₄N)₂[I]). The recrystallization of (Me₄N)₂[II] from N,N-dimethylformamide (DMF) gives compound (Me₄N)[Mo₂S₂O₂Cl₃(DMF)₃] ((Me₄N)[III]). The oxidation of (Et₄N)₂[I] with iodine in DMF affords the earlier described complex [Mo₂S₂O₂(DMF)₆]I₂ ([IV]I ₂). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924-1059926). Thus, several complexes in which the binuclear fragment {Mo₂S₂O₂}²⁺ has a labile coordination environment were synthesized and characterized.

Язык оригинала	английский
Страницы (с-по)	759-764
Число страниц	6
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	41
Номер выпуска	11
DOI	https://doi.org/10.1134/S1070328415110056
Состояние	Опубликовано - 1 нояб. 2015

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title = "Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands",

abstract = "Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I 2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924-1059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized.",

author = "Ogienko, {D. S.} and Smolentsev, {A. I.} and Bashirov, {D. A.} and Afonin, {M. Yu} and Petrov, {P. A.} and Konchenko, {S. N.}",

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Syntheses and structures of complexes {Mo₂S₂O₂}²⁺ with labile Cl^- and DMF ligands. / Ogienko, D. S.; Smolentsev, A. I.; Bashirov, D. A. и др.

В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 41, № 11, 01.11.2015, стр. 759-764.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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T1 - Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands

AU - Ogienko, D. S.

AU - Smolentsev, A. I.

AU - Bashirov, D. A.

AU - Afonin, M. Yu

AU - Petrov, P. A.

AU - Konchenko, S. N.

PY - 2015/11/1

Y1 - 2015/11/1

N2 - Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I 2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924-1059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized.

AB - Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I 2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924-1059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized.

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