Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine

O. G. Shakirova; L. G. Lavrenova; N. V. Kuratieva; A. S. Bogomyakov; L. A. Sheludyakova; A. P. Mosalkova; Yu V. Grigoriev

doi:10.1134/S0022476617050092

Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine

O. G. Shakirova, L. G. Lavrenova, N. V. Kuratieva, A. S. Bogomyakov, L. A. Sheludyakova, A. P. Mosalkova, Yu V. Grigoriev

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

Iron(II) dicyanamide and isothiocyanate compounds with 2-(2-tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL₂(C₂N₃)₂]•2H₂O (I) and [FeL₂(NCS)₂]H₂O (II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μ_eff(Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K.

Язык оригинала	английский
Страницы (с-по)	919-925
Число страниц	7
Журнал	Journal of Structural Chemistry
Том	58
Номер выпуска	5
DOI	https://doi.org/10.1134/S0022476617050092
Состояние	Опубликовано - 1 сент. 2017

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10.1134/S0022476617050092

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title = "Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine",

abstract = "Iron(II) dicyanamide and isothiocyanate compounds with 2-(2-tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL2(C2N3)2]•2H2O (I) and [FeL2(NCS)2]H2O (II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μeff(Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K.",

keywords = "2-(2-tert-butyltetrazol-5-yl)pyridine, coordination compounds, iron(II), magnetic properties, structure, synthesis, TRANSITION, SPIN-CROSSOVER, LIGAND",

author = "Shakirova, {O. G.} and Lavrenova, {L. G.} and Kuratieva, {N. V.} and Bogomyakov, {A. S.} and Sheludyakova, {L. A.} and Mosalkova, {A. P.} and Grigoriev, {Yu V.}",

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doi = "10.1134/S0022476617050092",

language = "English",

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Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine. / Shakirova, O. G.; Lavrenova, L. G.; Kuratieva, N. V. и др.

В: Journal of Structural Chemistry, Том 58, № 5, 01.09.2017, стр. 919-925.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine

AU - Shakirova, O. G.

AU - Lavrenova, L. G.

AU - Kuratieva, N. V.

AU - Bogomyakov, A. S.

AU - Sheludyakova, L. A.

AU - Mosalkova, A. P.

AU - Grigoriev, Yu V.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - Iron(II) dicyanamide and isothiocyanate compounds with 2-(2-tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL2(C2N3)2]•2H2O (I) and [FeL2(NCS)2]H2O (II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μeff(Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K.

AB - Iron(II) dicyanamide and isothiocyanate compounds with 2-(2-tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL2(C2N3)2]•2H2O (I) and [FeL2(NCS)2]H2O (II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μeff(Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K.

KW - 2-(2-tert-butyltetrazol-5-yl)pyridine

KW - coordination compounds

KW - iron(II)

KW - magnetic properties

KW - structure

KW - synthesis

KW - TRANSITION

KW - SPIN-CROSSOVER

KW - LIGAND

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M3 - Article

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EP - 925

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

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