Study of product composition of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium

Maxim Klyuchenko, Pulat Kadirov, Anastasiya Kuznetsova, Andrei Potapov

Результат исследования: Публикации в книгах, отчётах, сборниках, трудах конференцийстатья в сборнике материалов конференциинаучнаярецензирование

Аннотация

Influence of reagent ratio on the composition of products of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium (potassium hydroxide - dimethyl sulfoxide) was investigated using GC/MS technique. It was found that nucleophilic substitution reaction is always accompanied by elimination reactions (dehydrobromination and debromination). In addition to 1,1,2,2-tetra(azol-1-yl)ethane, 1,1,2-tri(azol-1-yl)ethenes and 1,2-di(azol-1-yl)ethenes, as well as 1,2-di(azol-1-yl)-1-bromoethenes were detected. Reaction pathway that explains the formation of all major products was proposed.

Язык оригиналаанглийский
Название основной публикации19TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY
РедакторыJA Seijas, MPV Tato, SK Lin
ИздательMDPI AG
Число страниц6
DOI
СостояниеОпубликовано - 2015
Опубликовано для внешнего пользованияДа
Событие19th International Electronic Conference on Synthetic Organic Chemistry -
Продолжительность: 1 ноя 201530 ноя 2015

Конференция

Конференция19th International Electronic Conference on Synthetic Organic Chemistry
Период01.11.201530.11.2015

Цитировать

Klyuchenko, M., Kadirov, P., Kuznetsova, A., & Potapov, A. (2015). Study of product composition of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium. В JA. Seijas, MPV. Tato, & SK. Lin (Ред.), 19TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY MDPI AG. https://doi.org/10.3390/ecsoc-19-a039