Structure of Cu(II) and Pd(II) complexes with 2-(2,2-dimethylhydrazone)pentanone-4

N. V. Kuratieva, E. S. Vikulova, A. D. Shushanyan, N. S. Nikolaeva, S. I. Dorovskikh, N. S. Mikhaleva, N. B. Morozova

Результат исследования: Научные публикации в периодических изданияхстатья

4 Цитирования (Scopus)

Аннотация

Palladium(II) and copper(II) complexes with 2-(2,2-dimethylhydrazone) pentanone-4 are synthesized for the first time. The compounds are characterized by IR and NMR spectroscopy, elemental and single crystal X-ray diffraction analyses. The palladium complex crystallizes in the space group I41/a; the copper complex crystallizes in the space group P1̅. Both compounds are molecular; the palladium chelate core has a distorted square geometry and that of copper has a distorted tetrahedral geometry. The average M–O and M–N bond lengths are respectively 1.9808(15) Å and 2.0427(17) Å for M = Pd, 1.915(8) Å and 1.97(1) Å for M = Cu. The chelate O–M–N angles are 88.32(7)-91.67(7)° for M = Pd, 93.37(4)-99.02(5)° for M = Cu.

Язык оригиналаанглийский
Страницы (с-по)1004-1008
Число страниц5
ЖурналJournal of Structural Chemistry
Том58
Номер выпуска5
DOI
СостояниеОпубликовано - 1 сен 2017

    Fingerprint

Цитировать