Structure of Cu(II) and Pd(II) complexes with 2-(2,2-dimethylhydrazone)pentanone-4

N. V. Kuratieva; E. S. Vikulova; A. D. Shushanyan; N. S. Nikolaeva; S. I. Dorovskikh; N. S. Mikhaleva; N. B. Morozova

doi:10.1134/S0022476617050213

Structure of Cu(II) and Pd(II) complexes with 2-(2,2-dimethylhydrazone)pentanone-4

N. V. Kuratieva, E. S. Vikulova, A. D. Shushanyan, N. S. Nikolaeva, S. I. Dorovskikh, N. S. Mikhaleva, N. B. Morozova

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

6 Цитирования (Scopus)

Аннотация

Palladium(II) and copper(II) complexes with 2-(2,2-dimethylhydrazone) pentanone-4 are synthesized for the first time. The compounds are characterized by IR and NMR spectroscopy, elemental and single crystal X-ray diffraction analyses. The palladium complex crystallizes in the space group I4₁/a; the copper complex crystallizes in the space group P1̅. Both compounds are molecular; the palladium chelate core has a distorted square geometry and that of copper has a distorted tetrahedral geometry. The average M–O and M–N bond lengths are respectively 1.9808(15) Å and 2.0427(17) Å for M = Pd, 1.915(8) Å and 1.97(1) Å for M = Cu. The chelate O–M–N angles are 88.32(7)-91.67(7)° for M = Pd, 93.37(4)-99.02(5)° for M = Cu.

Язык оригинала	английский
Страницы (с-по)	1004-1008
Число страниц	5
Журнал	Journal of Structural Chemistry
Том	58
Номер выпуска	5
DOI	https://doi.org/10.1134/S0022476617050213
Состояние	Опубликовано - 1 сен 2017

Доступ к документу

10.1134/S0022476617050213

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title = "Structure of Cu(II) and Pd(II) complexes with 2-(2,2-dimethylhydrazone)pentanone-4",

abstract = "Palladium(II) and copper(II) complexes with 2-(2,2-dimethylhydrazone) pentanone-4 are synthesized for the first time. The compounds are characterized by IR and NMR spectroscopy, elemental and single crystal X-ray diffraction analyses. The palladium complex crystallizes in the space group I41/a; the copper complex crystallizes in the space group P1̅. Both compounds are molecular; the palladium chelate core has a distorted square geometry and that of copper has a distorted tetrahedral geometry. The average M–O and M–N bond lengths are respectively 1.9808(15) {\AA} and 2.0427(17) {\AA} for M = Pd, 1.915(8) {\AA} and 1.97(1) {\AA} for M = Cu. The chelate O–M–N angles are 88.32(7)-91.67(7)° for M = Pd, 93.37(4)-99.02(5)° for M = Cu.",

keywords = "copper(II), palladium(II), single crystal X-ray diffraction, β-iminoketone, PALLADIUM, CHEMICAL-VAPOR-DEPOSITION, MEMBRANES, PRECURSORS, beta-iminoketone",

author = "Kuratieva, {N. V.} and Vikulova, {E. S.} and Shushanyan, {A. D.} and Nikolaeva, {N. S.} and Dorovskikh, {S. I.} and Mikhaleva, {N. S.} and Morozova, {N. B.}",

year = "2017",

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Structure of Cu(II) and Pd(II) complexes with 2-(2,2-dimethylhydrazone)pentanone-4. / Kuratieva, N. V.; Vikulova, E. S.; Shushanyan, A. D.; Nikolaeva, N. S.; Dorovskikh, S. I.; Mikhaleva, N. S.; Morozova, N. B.

В: Journal of Structural Chemistry, Том 58, № 5, 01.09.2017, стр. 1004-1008.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Structure of Cu(II) and Pd(II) complexes with 2-(2,2-dimethylhydrazone)pentanone-4

AU - Kuratieva, N. V.

AU - Vikulova, E. S.

AU - Shushanyan, A. D.

AU - Nikolaeva, N. S.

AU - Dorovskikh, S. I.

AU - Mikhaleva, N. S.

AU - Morozova, N. B.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - Palladium(II) and copper(II) complexes with 2-(2,2-dimethylhydrazone) pentanone-4 are synthesized for the first time. The compounds are characterized by IR and NMR spectroscopy, elemental and single crystal X-ray diffraction analyses. The palladium complex crystallizes in the space group I41/a; the copper complex crystallizes in the space group P1̅. Both compounds are molecular; the palladium chelate core has a distorted square geometry and that of copper has a distorted tetrahedral geometry. The average M–O and M–N bond lengths are respectively 1.9808(15) Å and 2.0427(17) Å for M = Pd, 1.915(8) Å and 1.97(1) Å for M = Cu. The chelate O–M–N angles are 88.32(7)-91.67(7)° for M = Pd, 93.37(4)-99.02(5)° for M = Cu.

AB - Palladium(II) and copper(II) complexes with 2-(2,2-dimethylhydrazone) pentanone-4 are synthesized for the first time. The compounds are characterized by IR and NMR spectroscopy, elemental and single crystal X-ray diffraction analyses. The palladium complex crystallizes in the space group I41/a; the copper complex crystallizes in the space group P1̅. Both compounds are molecular; the palladium chelate core has a distorted square geometry and that of copper has a distorted tetrahedral geometry. The average M–O and M–N bond lengths are respectively 1.9808(15) Å and 2.0427(17) Å for M = Pd, 1.915(8) Å and 1.97(1) Å for M = Cu. The chelate O–M–N angles are 88.32(7)-91.67(7)° for M = Pd, 93.37(4)-99.02(5)° for M = Cu.

KW - copper(II)

KW - palladium(II)

KW - single crystal X-ray diffraction

KW - β-iminoketone

KW - PALLADIUM

KW - CHEMICAL-VAPOR-DEPOSITION

KW - MEMBRANES

KW - PRECURSORS

KW - beta-iminoketone

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VL - 58

SP - 1004

EP - 1008

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

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ER -