Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)

M. O. Barsukova; D. G. Samsonenko; S. A. Sapchenko; D. N. Dybtsev; V. P. Fedin

doi:10.1007/s11172-017-1910-9

Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)

M. O. Barsukova, D. G. Samsonenko, S. A. Sapchenko, D. N. Dybtsev, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H₂O)(bpdc)(im)₂] (1, bpdc^2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH₃)₂NH₂]₄[Cd₆(dmf)(bpdc)₈]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.

Язык оригинала	английский
Страницы (с-по)	1472-1477
Число страниц	6
Журнал	Russian Chemical Bulletin
Том	66
Номер выпуска	8
DOI	https://doi.org/10.1007/s11172-017-1910-9
Состояние	Опубликовано - 1 авг 2017

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10.1007/s11172-017-1910-9

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title = "Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)",

abstract = "The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.",

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Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II). / Barsukova, M. O.; Samsonenko, D. G.; Sapchenko, S. A.; Dybtsev, D. N.; Fedin, V. P.

В: Russian Chemical Bulletin, Том 66, № 8, 01.08.2017, стр. 1472-1477.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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T1 - Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)

AU - Barsukova, M. O.

AU - Samsonenko, D. G.

AU - Sapchenko, S. A.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2017/8/1

Y1 - 2017/8/1

N2 - The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.

AB - The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.

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KW - cadmium

KW - imidazole

KW - metal–organic framework

KW - X-ray diffraction

KW - ACID

KW - BUILDING UNITS

KW - MOFS

KW - COORDINATION POLYMERS

KW - metal-organic framework

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