Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)

M. O. Barsukova, D. G. Samsonenko, S. A. Sapchenko, D. N. Dybtsev, V. P. Fedin

Результат исследования: Научные публикации в периодических изданияхстатья

3 Цитирования (Scopus)

Аннотация

The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.

Язык оригиналаанглийский
Страницы (с-по)1472-1477
Число страниц6
ЖурналRussian Chemical Bulletin
Том66
Номер выпуска8
DOI
СостояниеОпубликовано - 1 авг 2017

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