Аннотация
The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.
Язык оригинала | английский |
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Страницы (с-по) | 1472-1477 |
Число страниц | 6 |
Журнал | Russian Chemical Bulletin |
Том | 66 |
Номер выпуска | 8 |
DOI | |
Состояние | Опубликовано - 1 авг 2017 |