Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt

D. B. Vasilchenko; P. A. Topchiyan; S. V. Tkachev; I. A. Baidina; I. V. Korolkov; E. Yu Filatov; D. G. Sheven

doi:10.1134/S0022476619080122

Structure and Properties of (C₄N₂H₁₂)[Pt(NO₃)₆] Salt

D. B. Vasilchenko, P. A. Topchiyan, S. V. Tkachev, I. A. Baidina, I. V. Korolkov, E. Yu Filatov, D. G. Sheven

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

2 Цитирования (Scopus)

Аннотация

From a nitrate solution of platinum(IV) hydroxide, (C₄N₂H₁₂)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)Å, b= 12.919(1) Å, c = 9.889(9)Å, β = 08.625(4)°, space group C2/c, Z=4, ρ_calc ⁼ 2.306 g/cm³. In the structure, [Pt(NO₃)₆]²⁻ anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO₃)₆]²⁻ and [Pt₂(ώ-OH)₂(NO₃)₈]²⁻ anionic platinum nitrato complexes a relationship between the structure and ¹⁹⁵Pt MAS NMR spectra is shown.

Язык оригинала	английский
Страницы (с-по)	1327-1334
Число страниц	8
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	8
DOI	https://doi.org/10.1134/S0022476619080122
Состояние	Опубликовано - 1 авг. 2019

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10.1134/S0022476619080122

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title = "Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt",

abstract = "From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1){\AA}, b= 12.919(1) {\AA}, c = 9.889(9){\AA}, β = 08.625(4)°, space group C2/c, Z=4, ρcalc = 2.306 g/cm3. In the structure, [Pt(NO3)6]2− anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)6]2− and [Pt2(ώ-OH)2(NO3)8]2− anionic platinum nitrato complexes a relationship between the structure and 195Pt MAS NMR spectra is shown.",

keywords = "MAS NMR, nitrato complexes, piperazine, platinum, X-ray crystallographic analysis, NANOPARTICLES, STATE, PT-195 NMR, CATALYST, PLATINUM(IV)",

author = "Vasilchenko, {D. B.} and Topchiyan, {P. A.} and Tkachev, {S. V.} and Baidina, {I. A.} and Korolkov, {I. V.} and Filatov, {E. Yu} and Sheven, {D. G.}",

year = "2019",

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Structure and Properties of (C₄N₂H₁₂)[Pt(NO₃)₆] Salt. / Vasilchenko, D. B.; Topchiyan, P. A.; Tkachev, S. V. и др.

В: Journal of Structural Chemistry, Том 60, № 8, 01.08.2019, стр. 1327-1334.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt

AU - Vasilchenko, D. B.

AU - Topchiyan, P. A.

AU - Tkachev, S. V.

AU - Baidina, I. A.

AU - Korolkov, I. V.

AU - Filatov, E. Yu

AU - Sheven, D. G.

PY - 2019/8/1

Y1 - 2019/8/1

N2 - From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)Å, b= 12.919(1) Å, c = 9.889(9)Å, β = 08.625(4)°, space group C2/c, Z=4, ρcalc = 2.306 g/cm3. In the structure, [Pt(NO3)6]2− anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)6]2− and [Pt2(ώ-OH)2(NO3)8]2− anionic platinum nitrato complexes a relationship between the structure and 195Pt MAS NMR spectra is shown.

AB - From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)Å, b= 12.919(1) Å, c = 9.889(9)Å, β = 08.625(4)°, space group C2/c, Z=4, ρcalc = 2.306 g/cm3. In the structure, [Pt(NO3)6]2− anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)6]2− and [Pt2(ώ-OH)2(NO3)8]2− anionic platinum nitrato complexes a relationship between the structure and 195Pt MAS NMR spectra is shown.

KW - MAS NMR

KW - nitrato complexes

KW - piperazine

KW - platinum

KW - X-ray crystallographic analysis

KW - NANOPARTICLES

KW - STATE

KW - PT-195 NMR

KW - CATALYST

KW - PLATINUM(IV)

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JO - Journal of Structural Chemistry

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SN - 0022-4766

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