Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt

D. B. Vasilchenko, P. A. Topchiyan, S. V. Tkachev, I. A. Baidina, I. V. Korolkov, E. Yu Filatov, D. G. Sheven

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)Å, b= 12.919(1) Å, c = 9.889(9)Å, β = 08.625(4)°, space group C2/c, Z=4, ρcalc = 2.306 g/cm3. In the structure, [Pt(NO3)6]2− anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)6]2− and [Pt2(ώ-OH)2(NO3)8]2− anionic platinum nitrato complexes a relationship between the structure and 195Pt MAS NMR spectra is shown.

Язык оригиналаанглийский
Страницы (с-по)1327-1334
Число страниц8
ЖурналJournal of Structural Chemistry
Том60
Номер выпуска8
DOI
СостояниеОпубликовано - 1 авг 2019

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Vasilchenko, D. B., Topchiyan, P. A., Tkachev, S. V., Baidina, I. A., Korolkov, I. V., Filatov, E. Y., & Sheven, D. G. (2019). Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt. Journal of Structural Chemistry, 60(8), 1327-1334. https://doi.org/10.1134/S0022476619080122