Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion

T. I. Lappi; Ya M. Gayfulin; A. I. Smolentsev; Yu V. Mironov

doi:10.1134/S002247661704031X

Structural characterization of a bioctahedral cluster [Re₁₂CS₁₄(μ-SO₂)(μ-S)₂(CN)₆]^6– anion

T. I. Lappi, Ya M. Gayfulin, A. I. Smolentsev, Yu V. Mironov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

The [Zn(H₂O)₄]₃[Re₁₂CS₁₄(μ-SO₂)(μ-S)₂(CN)₆]_0.875[Re₁₂CS₁₄(μ-S)₃(CN)₆]_0.125•6H₂O compound (1) containing a new [Re₁₂CS₁₄(μ-SO₂)(μ-S)₂(CN)₆]^6– cluster anion is synthesized by the reaction of ZnCl₂ and K₆[Re₁₂CS₁₄(μ-S/SO/SO₂)₃(CN)6] in an aqueous solution and structurally characterized. Compound 1 crystallizes in a rhombic space group Pnma with the following unit cell parameters: a = 22.0834(7) Å, b = 28.2551(9) Å, c = 9.7775(3) Å, V = 6100.9(3) Å³, Z = 4, d_calc = 3.806 g/cm³. The crystal structure consists of two cluster anions in the ratio 7:1, occupying the same position, distorted [Zn(H₂O)₄]²⁺ cations, and solvate H₂O molecules linked by hydrogen bonds.

Язык оригинала	английский
Страницы (с-по)	835-837
Число страниц	3
Журнал	Journal of Structural Chemistry
Том	58
Номер выпуска	4
DOI	https://doi.org/10.1134/S002247661704031X
Состояние	Опубликовано - 1 июл. 2017

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10.1134/S002247661704031X

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@article{cff670d4b31a4ac8a0d4a1304bc8a2d5,

title = "Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion",

abstract = "The [Zn(H2O)4]3[Re12CS14(μ-SO2)(μ-S)2(CN)6]0.875[Re12CS14(μ-S)3(CN)6]0.125•6H2O compound (1) containing a new [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– cluster anion is synthesized by the reaction of ZnCl2 and K6[Re12CS14(μ-S/SO/SO2)3(CN)6] in an aqueous solution and structurally characterized. Compound 1 crystallizes in a rhombic space group Pnma with the following unit cell parameters: a = 22.0834(7) {\AA}, b = 28.2551(9) {\AA}, c = 9.7775(3) {\AA}, V = 6100.9(3) {\AA}3, Z = 4, dcalc = 3.806 g/cm3. The crystal structure consists of two cluster anions in the ratio 7:1, occupying the same position, distorted [Zn(H2O)4]2+ cations, and solvate H2O molecules linked by hydrogen bonds.",

keywords = "bioctahedral cluster complex, coordination polymer, crystal structure, rhenium, COMPLEX, RHENIUM CLUSTER",

author = "Lappi, {T. I.} and Gayfulin, {Ya M.} and Smolentsev, {A. I.} and Mironov, {Yu V.}",

note = "Publisher Copyright: {\textcopyright} 2017, Pleiades Publishing, Ltd.",

year = "2017",

month = jul,

day = "1",

doi = "10.1134/S002247661704031X",

language = "English",

volume = "58",

pages = "835--837",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "4",

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Structural characterization of a bioctahedral cluster [Re₁₂CS₁₄(μ-SO₂)(μ-S)₂(CN)₆]^6– anion. / Lappi, T. I.; Gayfulin, Ya M.; Smolentsev, A. I. и др.

В: Journal of Structural Chemistry, Том 58, № 4, 01.07.2017, стр. 835-837.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion

AU - Lappi, T. I.

AU - Gayfulin, Ya M.

AU - Smolentsev, A. I.

AU - Mironov, Yu V.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - The [Zn(H2O)4]3[Re12CS14(μ-SO2)(μ-S)2(CN)6]0.875[Re12CS14(μ-S)3(CN)6]0.125•6H2O compound (1) containing a new [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– cluster anion is synthesized by the reaction of ZnCl2 and K6[Re12CS14(μ-S/SO/SO2)3(CN)6] in an aqueous solution and structurally characterized. Compound 1 crystallizes in a rhombic space group Pnma with the following unit cell parameters: a = 22.0834(7) Å, b = 28.2551(9) Å, c = 9.7775(3) Å, V = 6100.9(3) Å3, Z = 4, dcalc = 3.806 g/cm3. The crystal structure consists of two cluster anions in the ratio 7:1, occupying the same position, distorted [Zn(H2O)4]2+ cations, and solvate H2O molecules linked by hydrogen bonds.

AB - The [Zn(H2O)4]3[Re12CS14(μ-SO2)(μ-S)2(CN)6]0.875[Re12CS14(μ-S)3(CN)6]0.125•6H2O compound (1) containing a new [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– cluster anion is synthesized by the reaction of ZnCl2 and K6[Re12CS14(μ-S/SO/SO2)3(CN)6] in an aqueous solution and structurally characterized. Compound 1 crystallizes in a rhombic space group Pnma with the following unit cell parameters: a = 22.0834(7) Å, b = 28.2551(9) Å, c = 9.7775(3) Å, V = 6100.9(3) Å3, Z = 4, dcalc = 3.806 g/cm3. The crystal structure consists of two cluster anions in the ratio 7:1, occupying the same position, distorted [Zn(H2O)4]2+ cations, and solvate H2O molecules linked by hydrogen bonds.

KW - bioctahedral cluster complex

KW - coordination polymer

KW - crystal structure

KW - rhenium

KW - COMPLEX

KW - RHENIUM CLUSTER

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U2 - 10.1134/S002247661704031X

DO - 10.1134/S002247661704031X

M3 - Article

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VL - 58

SP - 835

EP - 837

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -