@article{ed2ee119168c43e7828c06b9fb9e4e23,
title = "Stereoselectivity of formation of monoterpene – Amino acids hybrid molecules in the reaction of monoterpene nitroso chlorides with α-amino acid derivatives",
abstract = "Reaction of nitrosochlorides of natural monoterpene hydrocarbons (+)-3-carene and (−)-α-pinene with L-amino acids and their methyl esters results in stereoselective formation of terpene–amino acids hybrids, which belong to the series of α-substituted amino oximes. The reaction with an excess of racemic DL-amino acids and their derivatives induces partial resolution of the amino acid components and formation of the diastereomeric mixtures of the terpene–amino acids hybrids, with diastereomeric excess varying from 0 to 100%.",
keywords = "(+)-3-Carene, (−)-α-Pinene, Amino acids, Diastereoselectivity, Nitroso chlorides, Magnetic Resonance Spectroscopy, Amino Acids/chemistry, Stereoisomerism, Monoterpenes/chemistry, Terpenes/chemistry, COORDINATION CHEMISTRY, ZN-II, NATURAL MONOTERPENES, CRYSTAL-STRUCTURES, ALDEHYDES, H2L1, (+)-3-CARENE, BINUCLEAR COMPLEXES, (-)-alpha-Pinene, LIGANDS, II COMPLEXES",
author = "Marenin, {K. S.} and Gatilov, {Yu V.} and Agafontsev, {A. M.} and Tkachev, {A. V.}",
note = "Copyright {\textcopyright} 2016 Elsevier Inc. All rights reserved.",
year = "2017",
month = jan,
day = "1",
doi = "10.1016/j.steroids.2016.09.016",
language = "English",
volume = "117",
pages = "112--119",
journal = "Steroids",
issn = "0039-128X",
publisher = "Elsevier Science Inc.",
}