Spin-crossover in iron(ii) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine

A. D. Ivanova; E. V. Korotaev; V. Yu Komarov; L. A. Sheludyakova; V. A. Varnek; L. G. Lavrenova

doi:10.1039/d0nj00474j

Spin-crossover in iron(ii) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine

A. D. Ivanova, E. V. Korotaev, V. Yu Komarov, L. A. Sheludyakova, V. A. Varnek, L. G. Lavrenova

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

1 Цитирования (Scopus)

Аннотация

New iron(ii) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L), in particular, [FeL₂]A₂·nH₂O (A = Br^- (I), NO₃^- (II), C₂N₃^- (III); n = 1 (I), 0.5 (II), 2 (III)) and [NiL₂]Br₂·1.23H₂O·3.33EtOH (IV), have been synthesized and studied using single-crystal and powder X-ray diffraction techniques, UV-vis (diffuse reflection), IR and Mössbauer spectroscopy, as well as static magnetic susceptibility measurements. According to the experimental μ_eff(T) curves all the studied iron(ii) compounds exhibit ¹A₁ ↔ ⁵T₂ spin-crossover.

Язык оригинала	английский
Страницы (с-по)	5834-5840
Число страниц	7
Журнал	New Journal of Chemistry
Том	44
Номер выпуска	15
DOI	https://doi.org/10.1039/d0nj00474j
Состояние	Опубликовано - 21 апр 2020

Доступ к документу

10.1039/d0nj00474j

Другие файлы и ссылки

Link to publication in Scopus

Fingerprint

Подробные сведения о темах исследования «Spin-crossover in iron(ii) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать

@article{cac1dbd3e532495c931e9eece7633251,

title = "Spin-crossover in iron(ii) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine",

abstract = "New iron(ii) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L), in particular, [FeL2]A2·nH2O (A = Br- (I), NO3- (II), C2N3- (III); n = 1 (I), 0.5 (II), 2 (III)) and [NiL2]Br2·1.23H2O·3.33EtOH (IV), have been synthesized and studied using single-crystal and powder X-ray diffraction techniques, UV-vis (diffuse reflection), IR and M{\"o}ssbauer spectroscopy, as well as static magnetic susceptibility measurements. According to the experimental μeff(T) curves all the studied iron(ii) compounds exhibit 1A1 ↔ 5T2 spin-crossover.",

keywords = "COMPLEXES, LIGAND",

author = "Ivanova, {A. D.} and Korotaev, {E. V.} and Komarov, {V. Yu} and Sheludyakova, {L. A.} and Varnek, {V. A.} and Lavrenova, {L. G.}",

year = "2020",

month = apr,

day = "21",

doi = "10.1039/d0nj00474j",

language = "English",

volume = "44",

pages = "5834--5840",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "ROYAL SOC CHEMISTRY",

number = "15",

}

Spin-crossover in iron(ii) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine. / Ivanova, A. D.; Korotaev, E. V.; Komarov, V. Yu; Sheludyakova, L. A.; Varnek, V. A.; Lavrenova, L. G.

В: New Journal of Chemistry, Том 44, № 15, 21.04.2020, стр. 5834-5840.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Spin-crossover in iron(ii) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine

AU - Ivanova, A. D.

AU - Korotaev, E. V.

AU - Komarov, V. Yu

AU - Sheludyakova, L. A.

AU - Varnek, V. A.

AU - Lavrenova, L. G.

PY - 2020/4/21

Y1 - 2020/4/21

N2 - New iron(ii) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L), in particular, [FeL2]A2·nH2O (A = Br- (I), NO3- (II), C2N3- (III); n = 1 (I), 0.5 (II), 2 (III)) and [NiL2]Br2·1.23H2O·3.33EtOH (IV), have been synthesized and studied using single-crystal and powder X-ray diffraction techniques, UV-vis (diffuse reflection), IR and Mössbauer spectroscopy, as well as static magnetic susceptibility measurements. According to the experimental μeff(T) curves all the studied iron(ii) compounds exhibit 1A1 ↔ 5T2 spin-crossover.

AB - New iron(ii) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L), in particular, [FeL2]A2·nH2O (A = Br- (I), NO3- (II), C2N3- (III); n = 1 (I), 0.5 (II), 2 (III)) and [NiL2]Br2·1.23H2O·3.33EtOH (IV), have been synthesized and studied using single-crystal and powder X-ray diffraction techniques, UV-vis (diffuse reflection), IR and Mössbauer spectroscopy, as well as static magnetic susceptibility measurements. According to the experimental μeff(T) curves all the studied iron(ii) compounds exhibit 1A1 ↔ 5T2 spin-crossover.

KW - COMPLEXES

KW - LIGAND

UR - http://www.scopus.com/inward/record.url?scp=85083638023&partnerID=8YFLogxK

U2 - 10.1039/d0nj00474j

DO - 10.1039/d0nj00474j

M3 - Article

AN - SCOPUS:85083638023

VL - 44

SP - 5834

EP - 5840

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 15

ER -