Аннотация
New iron(ii) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L), in particular, [FeL2]A2·nH2O (A = Br- (I), NO3- (II), C2N3- (III); n = 1 (I), 0.5 (II), 2 (III)) and [NiL2]Br2·1.23H2O·3.33EtOH (IV), have been synthesized and studied using single-crystal and powder X-ray diffraction techniques, UV-vis (diffuse reflection), IR and Mössbauer spectroscopy, as well as static magnetic susceptibility measurements. According to the experimental μeff(T) curves all the studied iron(ii) compounds exhibit 1A1 ↔ 5T2 spin-crossover.
Язык оригинала | английский |
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Страницы (с-по) | 5834-5840 |
Число страниц | 7 |
Журнал | New Journal of Chemistry |
Том | 44 |
Номер выпуска | 15 |
DOI | |
Состояние | Опубликовано - 21 апр 2020 |