Simple synthetic protocol to obtain 3d-4f-heterometallic carboxylate complexes of N-heterocyclic carbenes

Stanislav A. Nikolaevskii; Pavel A. Petrov; Taisiya S. Sukhikh; Dmitriy S. Yambulatov; Mikhail A. Kiskin; Maxim N. Sokolov; Igor L. Eremenko

doi:10.1016/j.ica.2020.119643

Simple synthetic protocol to obtain 3d-4f-heterometallic carboxylate complexes of N-heterocyclic carbenes

Stanislav A. Nikolaevskii, Pavel A. Petrov, Taisiya S. Sukhikh, Dmitriy S. Yambulatov, Mikhail A. Kiskin, Maxim N. Sokolov, Igor L. Eremenko

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

A new approach to NHC-substituted 3d-4f-heterometallic complexes is suggested based on coordination of the free NHC with a pre-organized carboxylate 3d-4f-core. Following this route, two novel complexes with different heterometallic cores, Co₂La and Zn₂Tb, have been prepared.

Язык оригинала	английский
Номер статьи	119643
Число страниц	5
Журнал	Inorganica Chimica Acta
Том	508
DOI	https://doi.org/10.1016/j.ica.2020.119643
Состояние	Опубликовано - 1 авг 2020

Доступ к документу

10.1016/j.ica.2020.119643

Link to publication in Scopus

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Цитировать

Nikolaevskii, S. A., Petrov, P. A., Sukhikh, T. S., Yambulatov, D. S., Kiskin, M. A., Sokolov, M. N., & Eremenko, I. L. (2020). Simple synthetic protocol to obtain 3d-4f-heterometallic carboxylate complexes of N-heterocyclic carbenes. Inorganica Chimica Acta, 508, [119643]. https://doi.org/10.1016/j.ica.2020.119643

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title = "Simple synthetic protocol to obtain 3d-4f-heterometallic carboxylate complexes of N-heterocyclic carbenes",

abstract = "A new approach to NHC-substituted 3d-4f-heterometallic complexes is suggested based on coordination of the free NHC with a pre-organized carboxylate 3d-4f-core. Following this route, two novel complexes with different heterometallic cores, Co2La and Zn2Tb, have been prepared.",

keywords = "Carboxylate complexes, Cobalt, Heterometallic complexes, Lanthanides, N-heterocyclic carbenes, Zinc, DEPROTONATION, PHOTOLUMINESCENCE, STEREOCHEMISTRY, REACTIVITY, HETEROMETALLIC COMPLEXES, LUMINESCENCE, CHEMISTRY, GENERATION, CATALYTIC-ACTIVITY, METAL-COMPLEXES",

author = "Nikolaevskii, {Stanislav A.} and Petrov, {Pavel A.} and Sukhikh, {Taisiya S.} and Yambulatov, {Dmitriy S.} and Kiskin, {Mikhail A.} and Sokolov, {Maxim N.} and Eremenko, {Igor L.}",

year = "2020",

month = aug,

day = "1",

doi = "10.1016/j.ica.2020.119643",

language = "English",

volume = "508",

journal = "Inorganica Chimica Acta",

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Simple synthetic protocol to obtain 3d-4f-heterometallic carboxylate complexes of N-heterocyclic carbenes. / Nikolaevskii, Stanislav A.; Petrov, Pavel A.; Sukhikh, Taisiya S.; Yambulatov, Dmitriy S.; Kiskin, Mikhail A.; Sokolov, Maxim N.; Eremenko, Igor L.

В: Inorganica Chimica Acta, Том 508, 119643, 01.08.2020.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Simple synthetic protocol to obtain 3d-4f-heterometallic carboxylate complexes of N-heterocyclic carbenes

AU - Nikolaevskii, Stanislav A.

AU - Petrov, Pavel A.

AU - Sukhikh, Taisiya S.

AU - Yambulatov, Dmitriy S.

AU - Kiskin, Mikhail A.

AU - Sokolov, Maxim N.

AU - Eremenko, Igor L.

PY - 2020/8/1

Y1 - 2020/8/1

N2 - A new approach to NHC-substituted 3d-4f-heterometallic complexes is suggested based on coordination of the free NHC with a pre-organized carboxylate 3d-4f-core. Following this route, two novel complexes with different heterometallic cores, Co2La and Zn2Tb, have been prepared.

AB - A new approach to NHC-substituted 3d-4f-heterometallic complexes is suggested based on coordination of the free NHC with a pre-organized carboxylate 3d-4f-core. Following this route, two novel complexes with different heterometallic cores, Co2La and Zn2Tb, have been prepared.

KW - Carboxylate complexes

KW - Cobalt

KW - Heterometallic complexes

KW - Lanthanides

KW - N-heterocyclic carbenes

KW - Zinc

KW - DEPROTONATION

KW - PHOTOLUMINESCENCE

KW - STEREOCHEMISTRY

KW - REACTIVITY

KW - HETEROMETALLIC COMPLEXES

KW - LUMINESCENCE

KW - CHEMISTRY

KW - GENERATION

KW - CATALYTIC-ACTIVITY

KW - METAL-COMPLEXES

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U2 - 10.1016/j.ica.2020.119643

DO - 10.1016/j.ica.2020.119643

M3 - Article

AN - SCOPUS:85082870933

VL - 508

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 119643

ER -