Simple synthesis of pyrazole-derived dithioethers

Nina P. Chernova; Nurgul A. Pirmanova; Tolebi Dzhienalyev; Andrei S. Potapov

doi:10.1016/j.proche.2015.10.044

Simple synthesis of pyrazole-derived dithioethers

Nina P. Chernova, Nurgul A. Pirmanova, Tolebi Dzhienalyev, Andrei S. Potapov

Результат исследования: Публикации в книгах, отчётах, сборниках, трудах конференций › статья в сборнике материалов конференции › научная › рецензирование

Аннотация

A number of pyrazole-derived dithioethers were prepared by the reaction of diisothiuronium salts and 2-(3,5-dimethylpyrazol-1-yl)ethanol tosylate in a basic aqueous solution. Diisothiuronium salts were prepared by the reaction of thiourea with alpha,omega-dibromoalkanes containing from two to nine methylene groups. The use of these salts allowed in situ generation ions dithiolate, thus eliminating the need to use hazardous dimercaptans. (c) 2015 Published by Elsevier B.V.

Язык оригинала	английский
Название основной публикации	16TH INTERNATIONAL SCIENTIFIC CONFERENCE CHEMISTRY AND CHEMICAL ENGINEERING IN XXI CENTURY DEDICATED TO PROFESSOR L.P. KULYOV (CCE 2015)
Редакторы	E Korotkova
Издатель	Elsevier Science B.V.
Страницы	277-281
Число страниц	5
DOI	https://doi.org/10.1016/j.proche.2015.10.044
Состояние	Опубликовано - 2015
Опубликовано для внешнего пользования	Да
Событие	16th International Scientific Conference on Chemistry and Chemical Engineering in XXI century (CCE2015) - Tomsk Продолжительность: 25 мая 2015 → 29 мая 2015

Серия публикаций

Название	Procedia Chemistry
Издатель	ELSEVIER SCIENCE BV
Том	15
ISSN (печатное издание)	1876-6196

Конференция

Конференция	16th International Scientific Conference on Chemistry and Chemical Engineering in XXI century (CCE2015)
Город	Tomsk
Период	25.05.2015 → 29.05.2015

Доступ к документу

10.1016/j.proche.2015.10.044

Цитировать

Chernova, N. P., Pirmanova, N. A., Dzhienalyev, T., & Potapov, A. S. (2015). Simple synthesis of pyrazole-derived dithioethers. В E. Korotkova (Ред.), 16TH INTERNATIONAL SCIENTIFIC CONFERENCE CHEMISTRY AND CHEMICAL ENGINEERING IN XXI CENTURY DEDICATED TO PROFESSOR L.P. KULYOV (CCE 2015) (стр. 277-281). (Procedia Chemistry; Том 15). Elsevier Science B.V.. https://doi.org/10.1016/j.proche.2015.10.044

Chernova, Nina P. ; Pirmanova, Nurgul A. ; Dzhienalyev, Tolebi ; Potapov, Andrei S. / Simple synthesis of pyrazole-derived dithioethers. 16TH INTERNATIONAL SCIENTIFIC CONFERENCE CHEMISTRY AND CHEMICAL ENGINEERING IN XXI CENTURY DEDICATED TO PROFESSOR L.P. KULYOV (CCE 2015). редактор / E Korotkova. Elsevier Science B.V., 2015. стр. 277-281 (Procedia Chemistry).

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title = "Simple synthesis of pyrazole-derived dithioethers",

abstract = "A number of pyrazole-derived dithioethers were prepared by the reaction of diisothiuronium salts and 2-(3,5-dimethylpyrazol-1-yl)ethanol tosylate in a basic aqueous solution. Diisothiuronium salts were prepared by the reaction of thiourea with alpha,omega-dibromoalkanes containing from two to nine methylene groups. The use of these salts allowed in situ generation ions dithiolate, thus eliminating the need to use hazardous dimercaptans. (c) 2015 Published by Elsevier B.V.",

keywords = "pyrazole, thioether ligands, thiourea, thiuronium salts, hybrid ligands, CRYSTAL-STRUCTURES, STRUCTURAL-ANALYSIS, NMR-SPECTROSCOPY, LIGANDS, COMPLEXES, THIOETHER, 1,8-BIS(3,5-DIMETHYL-1-PYRAZOLYL)-3,6-DITHIAOCTANE, DERIVATIVES, SYSTEMS, H-1",

author = "Chernova, {Nina P.} and Pirmanova, {Nurgul A.} and Tolebi Dzhienalyev and Potapov, {Andrei S.}",

year = "2015",

doi = "10.1016/j.proche.2015.10.044",

language = "English",

series = "Procedia Chemistry",

publisher = "Elsevier Science B.V.",

pages = "277--281",

editor = "E Korotkova",

booktitle = "16TH INTERNATIONAL SCIENTIFIC CONFERENCE CHEMISTRY AND CHEMICAL ENGINEERING IN XXI CENTURY DEDICATED TO PROFESSOR L.P. KULYOV (CCE 2015)",

address = "Netherlands",

note = "16th International Scientific Conference on Chemistry and Chemical Engineering in XXI century (CCE2015) ; Conference date: 25-05-2015 Through 29-05-2015",

}

Chernova, NP, Pirmanova, NA, Dzhienalyev, T & Potapov, AS 2015, Simple synthesis of pyrazole-derived dithioethers. в E Korotkova (ред.), 16TH INTERNATIONAL SCIENTIFIC CONFERENCE CHEMISTRY AND CHEMICAL ENGINEERING IN XXI CENTURY DEDICATED TO PROFESSOR L.P. KULYOV (CCE 2015). Procedia Chemistry, том. 15, Elsevier Science B.V., стр. 277-281, 16th International Scientific Conference on Chemistry and Chemical Engineering in XXI century (CCE2015), Tomsk, 25.05.2015. https://doi.org/10.1016/j.proche.2015.10.044

Simple synthesis of pyrazole-derived dithioethers. / Chernova, Nina P.; Pirmanova, Nurgul A.; Dzhienalyev, Tolebi; Potapov, Andrei S.

16TH INTERNATIONAL SCIENTIFIC CONFERENCE CHEMISTRY AND CHEMICAL ENGINEERING IN XXI CENTURY DEDICATED TO PROFESSOR L.P. KULYOV (CCE 2015). ред. / E Korotkova. Elsevier Science B.V., 2015. стр. 277-281 (Procedia Chemistry; Том 15).

Результат исследования: Публикации в книгах, отчётах, сборниках, трудах конференций › статья в сборнике материалов конференции › научная › рецензирование

TY - GEN

T1 - Simple synthesis of pyrazole-derived dithioethers

AU - Chernova, Nina P.

AU - Pirmanova, Nurgul A.

AU - Dzhienalyev, Tolebi

AU - Potapov, Andrei S.

PY - 2015

Y1 - 2015

N2 - A number of pyrazole-derived dithioethers were prepared by the reaction of diisothiuronium salts and 2-(3,5-dimethylpyrazol-1-yl)ethanol tosylate in a basic aqueous solution. Diisothiuronium salts were prepared by the reaction of thiourea with alpha,omega-dibromoalkanes containing from two to nine methylene groups. The use of these salts allowed in situ generation ions dithiolate, thus eliminating the need to use hazardous dimercaptans. (c) 2015 Published by Elsevier B.V.

AB - A number of pyrazole-derived dithioethers were prepared by the reaction of diisothiuronium salts and 2-(3,5-dimethylpyrazol-1-yl)ethanol tosylate in a basic aqueous solution. Diisothiuronium salts were prepared by the reaction of thiourea with alpha,omega-dibromoalkanes containing from two to nine methylene groups. The use of these salts allowed in situ generation ions dithiolate, thus eliminating the need to use hazardous dimercaptans. (c) 2015 Published by Elsevier B.V.

KW - pyrazole

KW - thioether ligands

KW - thiourea

KW - thiuronium salts

KW - hybrid ligands

KW - CRYSTAL-STRUCTURES

KW - STRUCTURAL-ANALYSIS

KW - NMR-SPECTROSCOPY

KW - LIGANDS

KW - COMPLEXES

KW - THIOETHER

KW - 1,8-BIS(3,5-DIMETHYL-1-PYRAZOLYL)-3,6-DITHIAOCTANE

KW - DERIVATIVES

KW - SYSTEMS

KW - H-1

U2 - 10.1016/j.proche.2015.10.044

DO - 10.1016/j.proche.2015.10.044

M3 - Conference contribution

T3 - Procedia Chemistry

SP - 277

EP - 281

BT - 16TH INTERNATIONAL SCIENTIFIC CONFERENCE CHEMISTRY AND CHEMICAL ENGINEERING IN XXI CENTURY DEDICATED TO PROFESSOR L.P. KULYOV (CCE 2015)

A2 - Korotkova, E

PB - Elsevier Science B.V.

T2 - 16th International Scientific Conference on Chemistry and Chemical Engineering in XXI century (CCE2015)

Y2 - 25 May 2015 through 29 May 2015

ER -

Chernova NP, Pirmanova NA, Dzhienalyev T, Potapov AS. Simple synthesis of pyrazole-derived dithioethers. В Korotkova E, редактор, 16TH INTERNATIONAL SCIENTIFIC CONFERENCE CHEMISTRY AND CHEMICAL ENGINEERING IN XXI CENTURY DEDICATED TO PROFESSOR L.P. KULYOV (CCE 2015). Elsevier Science B.V. 2015. стр. 277-281. (Procedia Chemistry). https://doi.org/10.1016/j.proche.2015.10.044