Self-assembly of Ag(I)-based complexes and layered coordination polymers bridged by (2-thiazolyl)sulfides

Maxim I. Rogovoy; Denis G. Samsonenko; Mariana I. Rakhmanova; Alexander V. Artem'ev

doi:10.1016/j.ica.2019.01.036

Self-assembly of Ag(I)-based complexes and layered coordination polymers bridged by (2-thiazolyl)sulfides

Maxim I. Rogovoy, Denis G. Samsonenko, Mariana I. Rakhmanova, Alexander V. Artem'ev

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

17 Цитирования (Scopus)

Аннотация

Dinuclear complex, [Ag₂(2-Mt)₂(MeCN)₂(NO₃)₂] (1) as well as layered (2D) coordination polymers (CPs), [Ag₂(2-Mt)₂(NO₃)₂]_n (2) and [Ag₄(2-Mt)₄(NO₃)₄·2H₂O]_n (3), are self-assembled from 2-(methylthio)thiazole (2-Mt) and AgNO₃ under different conditions. These compounds contain a [Ag₂(2-Mt)₂] unit consisting of two metal atoms bridged by 2-Mt ligands (μ₂-N,S) in head-to-tail (for 1 and 2) and head-to-head (for 3) manner. 2-(Methylthio)benzothiazole (2-Mbt) reacts with AgNO₃ to assemble complex [Ag₂(2-Mbt)₂(MeCN)₂(NO₃)₂] (4), showing interesting dual emission behavior associated with the presence of fluorescence and phosphorescence, contributions of which depends on the excitation wavelength.

Язык оригинала	английский
Страницы (с-по)	19-26
Число страниц	8
Журнал	Inorganica Chimica Acta
Том	489
DOI	https://doi.org/10.1016/j.ica.2019.01.036
Состояние	Опубликовано - 1 апр 2019

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10.1016/j.ica.2019.01.036

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@article{753336f00e05484eb1b720eeed854e31,

title = "Self-assembly of Ag(I)-based complexes and layered coordination polymers bridged by (2-thiazolyl)sulfides",

abstract = "Dinuclear complex, [Ag2(2-Mt)2(MeCN)2(NO3)2] (1) as well as layered (2D) coordination polymers (CPs), [Ag2(2-Mt)2(NO3)2]n (2) and [Ag4(2-Mt)4(NO3)4·2H2O]n (3), are self-assembled from 2-(methylthio)thiazole (2-Mt) and AgNO3 under different conditions. These compounds contain a [Ag2(2-Mt)2] unit consisting of two metal atoms bridged by 2-Mt ligands (μ2-N,S) in head-to-tail (for 1 and 2) and head-to-head (for 3) manner. 2-(Methylthio)benzothiazole (2-Mbt) reacts with AgNO3 to assemble complex [Ag2(2-Mbt)2(MeCN)2(NO3)2] (4), showing interesting dual emission behavior associated with the presence of fluorescence and phosphorescence, contributions of which depends on the excitation wavelength.",

keywords = "Coordination polymers, Dual-emission, Self-assembly, Silver(I), Thiazoles, Thioether ligands, AG(I) COMPLEXES, SILVER(I) COMPLEXES, CRYSTAL-STRUCTURE, SPECTROSCOPIC PROPERTIES, THIAZOLE, NETWORKS, SULFUR, LUMINESCENCE, CLUSTERS, DONOR LIGANDS",

author = "Rogovoy, {Maxim I.} and Samsonenko, {Denis G.} and Rakhmanova, {Mariana I.} and Artem'ev, {Alexander V.}",

year = "2019",

month = apr,

day = "1",

doi = "10.1016/j.ica.2019.01.036",

language = "English",

volume = "489",

pages = "19--26",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

Self-assembly of Ag(I)-based complexes and layered coordination polymers bridged by (2-thiazolyl)sulfides. / Rogovoy, Maxim I.; Samsonenko, Denis G.; Rakhmanova, Mariana I.; Artem'ev, Alexander V.

В: Inorganica Chimica Acta, Том 489, 01.04.2019, стр. 19-26.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Self-assembly of Ag(I)-based complexes and layered coordination polymers bridged by (2-thiazolyl)sulfides

AU - Rogovoy, Maxim I.

AU - Samsonenko, Denis G.

AU - Rakhmanova, Mariana I.

AU - Artem'ev, Alexander V.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - Dinuclear complex, [Ag2(2-Mt)2(MeCN)2(NO3)2] (1) as well as layered (2D) coordination polymers (CPs), [Ag2(2-Mt)2(NO3)2]n (2) and [Ag4(2-Mt)4(NO3)4·2H2O]n (3), are self-assembled from 2-(methylthio)thiazole (2-Mt) and AgNO3 under different conditions. These compounds contain a [Ag2(2-Mt)2] unit consisting of two metal atoms bridged by 2-Mt ligands (μ2-N,S) in head-to-tail (for 1 and 2) and head-to-head (for 3) manner. 2-(Methylthio)benzothiazole (2-Mbt) reacts with AgNO3 to assemble complex [Ag2(2-Mbt)2(MeCN)2(NO3)2] (4), showing interesting dual emission behavior associated with the presence of fluorescence and phosphorescence, contributions of which depends on the excitation wavelength.

AB - Dinuclear complex, [Ag2(2-Mt)2(MeCN)2(NO3)2] (1) as well as layered (2D) coordination polymers (CPs), [Ag2(2-Mt)2(NO3)2]n (2) and [Ag4(2-Mt)4(NO3)4·2H2O]n (3), are self-assembled from 2-(methylthio)thiazole (2-Mt) and AgNO3 under different conditions. These compounds contain a [Ag2(2-Mt)2] unit consisting of two metal atoms bridged by 2-Mt ligands (μ2-N,S) in head-to-tail (for 1 and 2) and head-to-head (for 3) manner. 2-(Methylthio)benzothiazole (2-Mbt) reacts with AgNO3 to assemble complex [Ag2(2-Mbt)2(MeCN)2(NO3)2] (4), showing interesting dual emission behavior associated with the presence of fluorescence and phosphorescence, contributions of which depends on the excitation wavelength.

KW - Coordination polymers

KW - Dual-emission

KW - Self-assembly

KW - Silver(I)

KW - Thiazoles

KW - Thioether ligands

KW - AG(I) COMPLEXES

KW - SILVER(I) COMPLEXES

KW - CRYSTAL-STRUCTURE

KW - SPECTROSCOPIC PROPERTIES

KW - THIAZOLE

KW - NETWORKS

KW - SULFUR

KW - LUMINESCENCE

KW - CLUSTERS

KW - DONOR LIGANDS

UR - http://www.scopus.com/inward/record.url?scp=85061174959&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2019.01.036

DO - 10.1016/j.ica.2019.01.036

M3 - Article

AN - SCOPUS:85061174959

VL - 489

SP - 19

EP - 26

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -