Self-Assembled Microporous M-HOFs Based on an Octahedral Rhenium Cluster with Benzimidazole

Dmitry I. Konovalov, Anton A. Ivanov, Yuri A. Vorotnikov, Natalia V. Kuratieva, Ilia V. Eltsov, Konstantin A. Kovalenko, Michael A. Shestopalov

Результат исследования: Научные публикации в периодических изданияхстатьярецензирование


Substitution of apical halide ligands in [{Re6Sei8}Xa6]3- (X = Cl, Br) by benzimidazole (bimzH) accompanied by a self-assembly process leads to the formation of microporous Re6-based hydrogen-bonded organic frameworks (Re6-HOFs) constructed on N-H···X hydrogen bonds and π- π-stacking interactions between bimzH ligands. Re6-HOFs demonstrate sorption properties with a Brunauer-Emmett-Teller surface area of up to 443 m2 g-1 and luminescence with a quantum yield and an emission lifetime of up to 0.16 and 16 μs, respectively. The compounds obtained complement small groups of transition-metal cluster-based HOFs, which are a perspective for the development of multifunctional frameworks.

Язык оригиналаанглийский
Страницы (с-по)14687-14696
Число страниц10
ЖурналInorganic Chemistry
Номер выпуска19
Ранняя дата в режиме онлайн13 сен 2021
СостояниеОпубликовано - 4 окт 2021

Предметные области OECD FOS+WOS



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