Selective oxidative intermolecular carbosulphenylation of aryl alkenes with thiols and nucleophilesviaa 1,2-dithioethane intermediate

Yuna Wang; Zaojuan Qi; Yanning Niu; Hua Feng; Enrico Benassi; Bo Qian

doi:10.1039/d1cc02517a

Selective oxidative intermolecular carbosulphenylation of aryl alkenes with thiols and nucleophilesviaa 1,2-dithioethane intermediate

Yuna Wang, Zaojuan Qi, Yanning Niu, Hua Feng, Enrico Benassi, Bo Qian

Кафедра органической химии ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

A periodate lithium-oxidized difunctionalisation of aryl alkenes with thiols and electron-rich aromatics was achieved, selectively affording more than thirty carbosulphenylated products. Both experiments and quantum chemical calculations demonstrated the radical-polar nature of the processes, and that 1,2-dithioethane and thiiranium ions might play the role of intermediates.

Язык оригинала	английский
Страницы (с-по)	7533-7536
Число страниц	4
Журнал	Chemical Communications
Том	57
Номер выпуска	61
DOI	https://doi.org/10.1039/d1cc02517a
Состояние	Опубликовано - 7 авг 2021

Предметные области OECD FOS+WOS

2.05 ТЕХНОЛОГИЯ МАТЕРИАЛОВ
2.04 ХИМИЧЕСКИЕ ТЕХНОЛОГИИ
1.04 ХИМИЧЕСКИЕ НАУКИ

Доступ к документу

10.1039/d1cc02517a

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abstract = "A periodate lithium-oxidized difunctionalisation of aryl alkenes with thiols and electron-rich aromatics was achieved, selectively affording more than thirty carbosulphenylated products. Both experiments and quantum chemical calculations demonstrated the radical-polar nature of the processes, and that 1,2-dithioethane and thiiranium ions might play the role of intermediates.",

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Selective oxidative intermolecular carbosulphenylation of aryl alkenes with thiols and nucleophilesviaa 1,2-dithioethane intermediate. / Wang, Yuna; Qi, Zaojuan; Niu, Yanning; Feng, Hua; Benassi, Enrico; Qian, Bo.

В: Chemical Communications, Том 57, № 61, 07.08.2021, стр. 7533-7536.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Selective oxidative intermolecular carbosulphenylation of aryl alkenes with thiols and nucleophilesviaa 1,2-dithioethane intermediate

AU - Wang, Yuna

AU - Qi, Zaojuan

AU - Niu, Yanning

AU - Feng, Hua

AU - Benassi, Enrico

AU - Qian, Bo

PY - 2021/8/7

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AB - A periodate lithium-oxidized difunctionalisation of aryl alkenes with thiols and electron-rich aromatics was achieved, selectively affording more than thirty carbosulphenylated products. Both experiments and quantum chemical calculations demonstrated the radical-polar nature of the processes, and that 1,2-dithioethane and thiiranium ions might play the role of intermediates.

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