Screw-like morphology of silicoaluminophosphate-11 (SAPO-11) crystallized in ethanol medium

I. A. Tiuliukova; N. A. Rudina; A. I. Lysikov; S. V. Cherepanova; E. V. Parkhomchuk

doi:10.1016/j.matlet.2018.05.118

Screw-like morphology of silicoaluminophosphate-11 (SAPO-11) crystallized in ethanol medium

I. A. Tiuliukova, N. A. Rudina, A. I. Lysikov, S. V. Cherepanova, E. V. Parkhomchuk

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

Silicoaluminophosphate-11 (SAPO-11) crystals were synthesized in different media – water and ethanol – by the two-stage hydrothermal method using ultrasonic pretreatment of precursor mixture. Changing of the synthesis medium from water to ethanol leads to transformation of SAPO-11 morphology: from pseudo-spherical aggregative crystals to novel screw-like morphology. SAPO-11 crystals, synthesized in ethanol medium (Et-SAPO-11), have remarkable textural properties: the greater values of BET surface area and micropore/mesopores volume, compared with crystals, obtained in the water medium (W-SAPO-11). Besides, the acidity of Et-SAPO-11 is lower than that of W-SAPO-11 due to hindered incorporation of silicon into aluminophosphate lattice in ethanol medium.

Язык оригинала	английский
Страницы (с-по)	61-64
Число страниц	4
Журнал	Materials Letters
Том	228
DOI	https://doi.org/10.1016/j.matlet.2018.05.118
Состояние	Опубликовано - 1 окт 2018

Доступ к документу

10.1016/j.matlet.2018.05.118

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title = "Screw-like morphology of silicoaluminophosphate-11 (SAPO-11) crystallized in ethanol medium",

abstract = "Silicoaluminophosphate-11 (SAPO-11) crystals were synthesized in different media – water and ethanol – by the two-stage hydrothermal method using ultrasonic pretreatment of precursor mixture. Changing of the synthesis medium from water to ethanol leads to transformation of SAPO-11 morphology: from pseudo-spherical aggregative crystals to novel screw-like morphology. SAPO-11 crystals, synthesized in ethanol medium (Et-SAPO-11), have remarkable textural properties: the greater values of BET surface area and micropore/mesopores volume, compared with crystals, obtained in the water medium (W-SAPO-11). Besides, the acidity of Et-SAPO-11 is lower than that of W-SAPO-11 due to hindered incorporation of silicon into aluminophosphate lattice in ethanol medium.",

keywords = "Crystal morphology, Ethanol medium, Porous materials, SAPO-11, Silicoaluminophosphate, Texture, SILICON, HYDROISOMERIZATION, MOLECULAR-SIEVES, NONAQUEOUS MEDIA, PT/SAPO-11, ALKENES, CATALYTIC-PROPERTIES, IMPROVEMENT",

author = "Tiuliukova, {I. A.} and Rudina, {N. A.} and Lysikov, {A. I.} and Cherepanova, {S. V.} and Parkhomchuk, {E. V.}",

year = "2018",

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doi = "10.1016/j.matlet.2018.05.118",

language = "English",

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journal = "Materials Letters",

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publisher = "Elsevier",

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Screw-like morphology of silicoaluminophosphate-11 (SAPO-11) crystallized in ethanol medium. / Tiuliukova, I. A.; Rudina, N. A.; Lysikov, A. I.; Cherepanova, S. V.; Parkhomchuk, E. V.

В: Materials Letters, Том 228, 01.10.2018, стр. 61-64.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Screw-like morphology of silicoaluminophosphate-11 (SAPO-11) crystallized in ethanol medium

AU - Tiuliukova, I. A.

AU - Rudina, N. A.

AU - Lysikov, A. I.

AU - Cherepanova, S. V.

AU - Parkhomchuk, E. V.

PY - 2018/10/1

Y1 - 2018/10/1

N2 - Silicoaluminophosphate-11 (SAPO-11) crystals were synthesized in different media – water and ethanol – by the two-stage hydrothermal method using ultrasonic pretreatment of precursor mixture. Changing of the synthesis medium from water to ethanol leads to transformation of SAPO-11 morphology: from pseudo-spherical aggregative crystals to novel screw-like morphology. SAPO-11 crystals, synthesized in ethanol medium (Et-SAPO-11), have remarkable textural properties: the greater values of BET surface area and micropore/mesopores volume, compared with crystals, obtained in the water medium (W-SAPO-11). Besides, the acidity of Et-SAPO-11 is lower than that of W-SAPO-11 due to hindered incorporation of silicon into aluminophosphate lattice in ethanol medium.

AB - Silicoaluminophosphate-11 (SAPO-11) crystals were synthesized in different media – water and ethanol – by the two-stage hydrothermal method using ultrasonic pretreatment of precursor mixture. Changing of the synthesis medium from water to ethanol leads to transformation of SAPO-11 morphology: from pseudo-spherical aggregative crystals to novel screw-like morphology. SAPO-11 crystals, synthesized in ethanol medium (Et-SAPO-11), have remarkable textural properties: the greater values of BET surface area and micropore/mesopores volume, compared with crystals, obtained in the water medium (W-SAPO-11). Besides, the acidity of Et-SAPO-11 is lower than that of W-SAPO-11 due to hindered incorporation of silicon into aluminophosphate lattice in ethanol medium.

KW - Crystal morphology

KW - Ethanol medium

KW - Porous materials

KW - SAPO-11

KW - Silicoaluminophosphate

KW - Texture

KW - SILICON

KW - HYDROISOMERIZATION

KW - MOLECULAR-SIEVES

KW - NONAQUEOUS MEDIA

KW - PT/SAPO-11

KW - ALKENES

KW - CATALYTIC-PROPERTIES

KW - IMPROVEMENT

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M3 - Article

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JO - Materials Letters

JF - Materials Letters

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